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Alfa Aesar™ Phenylmagnesium chloride, 1M in MeTHF

Chemical Identifiers

Chemical Name or Material Phenylmagnesium chloride
CAS 100-59-4
Molecular Formula C6H5MgCl
Formula Weight 136.86g/mol
MDL Number MFCD00000464
UN Number UN3399
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAH51157AE

 
alfa aesar™
H51157-AE
100mL CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAH51157AP

 
alfa aesar™
H51157-AP
500mL CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Quantity 100mL
Flash Point −17°C (1.4°F)
Concentration 1M in MeTHF
Quantity 100mL
Chemical Name or Material Phenylmagnesium chloride
CAS 100-59-4
Molecular Formula C6H5MgCl
Formula Weight 136.86g/mol
MDL Number MFCD00000464
UN Number UN3399
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H225-H261-H314-H302-H312
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Harmful if swallowed.
Harmful in contact with skin.
Health Hazard 3 GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
TSCA TSCA

Applications
Phenylmagnesium chloride is used primarily to add an iso-propyl group to carbonyl groups. This reagent can also be used as a strong base in aprotic solvents. It is also used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Solubility
It reacts violently with water.

Notes
Air & moisture sensitive. Incompatible with heat.

Safety and Handling

Danger

GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H225-H261-H314-H302-H312
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Harmful if swallowed.
Harmful in contact with skin.