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Alfa Aesar™ Phenyl phosphorodichloridate, 97%

$36.86 - $387.07

Chemical Identifiers

CAS 770-12-7
Molecular Formula C6H5Cl2O2P
Molecular Weight (g/mol) 210.978
MDL Number MFCD00002067
InChI Key TXFOLHZMICYNRM-UHFFFAOYSA-N
Synonym phenyl dichlorophosphate, phenyl phosphorodichloridate, dichlorophenoxyphosphine oxide, phosphorodichloridic acid, phenyl ester, phenylphosphoric dichloride, phenyl phosphorodichlorodate, phenoxydichlorophosphine oxide, phenyldichlorophosphate, phenoxyphosphoryl dichloride, phosphoroyl dichloride phenyl ester
PubChem CID 13038
IUPAC Name dichlorophosphoryloxybenzene
SMILES C1=CC=C(C=C1)OP(=O)(Cl)Cl
View More Specs

Products 3
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAA1047922 View Documents Alfa Aesar™
A1047922
100g Each for $92.99
 
AAA1047936 View Documents Alfa Aesar™
A1047936
500g Each for $387.07
 
AAA1047914 View Documents Alfa Aesar™
A1047914
25g Each for $36.86
 
Description

Description

Applications
Reagent for preparation of phosphate diesters.Phenyl phosphorodichloridate is used in the preparation of symmetrical phosphate diesters. It is used as a phosphorylating agent for alcohols and amines. It is also involved in the preparation of phenylphosphoro di-(1-imidazolidate) and 2-phenyl-bis-triazoloylphosphate, which is used in peptide synthesis. It plays a vital role in the Pfitzner-Moffatt oxidation which involves oxidation of alcohols to the corresponding aldehydes and ketones. Furthermore, it is utilized in Beckmann rearrangement for the preparation of N-phenylacetamide from acetophenone oxime.

Solubility
Immiscible with water.

Notes
Moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, alcohols and strong oxidizing agents.
Specifications

Chemical Identifiers

770-12-7
210.978
TXFOLHZMICYNRM-UHFFFAOYSA-N
13038
C1=CC=C(C=C1)OP(=O)(Cl)Cl
C6H5Cl2O2P
MFCD00002067
phenyl dichlorophosphate, phenyl phosphorodichloridate, dichlorophenoxyphosphine oxide, phosphorodichloridic acid, phenyl ester, phenylphosphoric dichloride, phenyl phosphorodichlorodate, phenoxydichlorophosphine oxide, phenyldichlorophosphate, phenoxyphosphoryl dichloride, phosphoroyl dichloride phenyl ester
dichlorophosphoryloxybenzene

Specifications

112°C (233°F)
-1°C
770-12-7
MFCD00002067
511863
TXFOLHZMICYNRM-UHFFFAOYSA-N
dichlorophosphoryloxybenzene
13038
97%
241°C to 243°C
100g
C6H5Cl2O2P
UN3265
phenyl dichlorophosphate, phenyl phosphorodichloridate, dichlorophenoxyphosphine oxide, phosphorodichloridic acid, phenyl ester, phenylphosphoric dichloride, phenyl phosphorodichlorodate, phenoxydichlorophosphine oxide, phenyldichlorophosphate, phenoxyphosphoryl dichloride, phosphoroyl dichloride phenyl ester
C1=CC=C(C=C1)OP(=O)(Cl)Cl
210.978
210.98
Phenyl phosphorodichloridate
Safety and Handling

Safety and Handling

GHS H Statement
H314-H318-H302
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

RTECSNumber : TD4393000

TSCA : TSCA