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Alfa Aesar™ Phenyl chlorothionoformate, 98+%

$104.27 - $104.27

Chemical Identifiers

Chemical Name or Material Phenyl chlorothionoformate
CAS 1005-56-7
Molecular Formula C7H5ClOS
Formula Weight 172.63
MDL Number MFCD00004920
UN Number UN3265
Beilstein 774830
Synonym Phenyl chlorothionocarbonate; Phenyl thionochloroformate
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL0083806

  SDS
alfa aesar™
L0083806*
5g Each for $104.27

AAL0083803

  SDS
alfa aesar™
L0083803
1g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAL0083814

  SDS
alfa aesar™
L0083814
25g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Formula Weight 172.63
Boiling Point 81° to 83°C (6mmHg)
Molecular Formula C7H5ClOS
Chemical Name or Material Phenyl chlorothionoformate
Health Hazard 3 GHS P Statement
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
Odor Acrid
Flash Point 81°C (177°F)
MDL Number MFCD00004920
Health Hazard 1 Danger
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Recommended Storage 2° to 8°C
UN Number UN3265
Synonym Phenyl chlorothionocarbonate; Phenyl thionochloroformate
Health Hazard 2 GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.
Assay ≥98%
Quantity 5g
Beilstein 774830
CAS 1005-56-7

Applications
Phenyl chlorothionoformate has been used in stereo directed synthesis of optically active, (-)-mintlactone, synthesis of peptide α-thioesters having a variety of C-terminal amino acids, synthesis of scyllo-inositol derivatives, thionocarbonylation of unprotected thymine nucleosides, preparation of phenoxythiocarbonyl esters of protected ribonucleosides. It is also used as a reagent in the thionocarbonylation of unprotected thymine nucleosides. It forms phenoxythiocarbonyl esters of protected ribonucleosides which can be reduced by tributyltin hydride to deoxyribonucleosides.

Solubility
Soluble in water.

Notes
Moisture, Heat Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

Safety and Handling

Danger

GHS P Statement
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.

2° to 8°C