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Nickel(II) chloride hexahydrate, 99.3% (metals basis), Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals 012372A3

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Catalog No. AA12372A3



Description

Description

It is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is used to prepare a wide array of complexes since water ligands can be easily replaced by amines, thioether, ammonia, and thiolates. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Specifications

Nickel(II) chloride hexahydrate
7791-20-0
2 kg
Cl2Ni·6H2O
Freely soluble in water. Soluble in ethylene glycol,ethanol,and ammonium hydroxide.
Odorless
1.92
140°C-H2O
Crystalline
99.3% (metals basis)
MFCD00149809
237.71 (129.60 Anhydrous)
Green crystals

Chemical Identifiers

7791-20-0
Cl2Ni·6H2O
MFCD00149809
Safety and Handling

Safety and Handling

P201-P202-P260-P264b-P270-P271-P272-P280-P281-P285-P301+P310-P302+P352-P304+P340-P305+P351+P338-P308+P313-P311-P330-P333+P313-P362-P501c

H301+H331-H315-H317-H319-H334-H341-H350i-H360D-H372

DOTInformation : DOT Class: 6.1, Packaging Group: III

EINECSNumber : 231-743-0

RTECSNumber : QR6480000

TSCA : Yes

Recommended Storage : Ambient temperatures

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