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Alfa Aesar™ N-Phenylbis(trifluoromethanesulfonimide), 99%

$83.80 - $322.35

Chemical Identifiers

Chemical Name or Material N-Phenylbis(trifluoromethanesulfonimide)
CAS 37595-74-7
Molecular Formula (CF3SO2)2NC6H5
Formula Weight 357.25g/mol
MDL Number MFCD00000404
Beilstein 1269141
Synonym N,N-Bis(trifluoromethanesulfonyl)aniline; Phenyl triflimide
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1253106

 
alfa aesar™
L12531-06
5g Each for $83.80

AAL1253114

 
alfa aesar™
L12531-14
25g Each for $322.35
Description & Specifications

Specifications

Melting Point 100° to 102°C
Quantity 5g
Chemical Name or Material N-Phenylbis(trifluoromethanesulfonimide)
CAS 37595-74-7
Assay 99%
Molecular Formula (CF3SO2)2NC6H5
Formula Weight 357.25g/mol
MDL Number MFCD00000404
Beilstein 1269141
Synonym N,N-Bis(trifluoromethanesulfonyl)aniline; Phenyl triflimide
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Applications
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation. Further, it is used in the enantioselective synthesis of beta-amino acids through the Mannich reaction. In addition to this, it is used in the preparation of sphingosine 1-phosphate-1 receptor agonists.

Solubility
Soluble in methanol. Slightly soluble in chloroform and ethyl acetate.

Notes
Hygroscopic. Store in a cool place. Moisture sensitive. Incompatible with strong oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.