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Alfa Aesar™ N-Hydroxyphthalimide, 98+%

$49.58 - $706.68

Chemical Identifiers

Chemical Name or Material N-Hydroxyphthalimide
CAS 524-38-9
Molecular Formula C8H5NO3
Formula Weight 163.13
MDL Number MFCD00005891
Beilstein 131208
Merck Index 14,4838
Synonym NHPI
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1386222

  SDS
alfa aesar™
A1386222
100g Each for $49.58

AAA138620E

  SDS
alfa aesar™
A138620E
2500g Each for $706.68

AAA1386236

  SDS
alfa aesar™
A1386236
500g Each for $176.30
Description & Specifications

Specifications

Formula Weight 163.13
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
MDL Number MFCD00005891
Merck Index 14,4838
TSCA TSCA
RTECS Number TI5200000
Beilstein 131208
Chemical Name or Material N-Hydroxyphthalimide
Melting Point ≈233°C (dec.)
Quantity 100g
Synonym NHPI
Molecular Formula C8H5NO3
CAS 524-38-9
Health Hazard 1 Warning
Assay ≥98%
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Applications
Aerobic oxidation of various alcohols has been accomplished by using a new catalytic system, N-hydroxyphthalimide (NHPI) combined with Co (acac). A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co (OAc) 2 was developed. Novel catalysis by N-hydroxyphthalimide in the oxidation of organic substrates by molecular oxygen was described. Free radical functionalization of organic compounds catalyzed by N-hydroxyphthalimide. Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions. Hydroxylation of polycyclic alkanes with molecular oxygen catalyzed by N-hydroxyphthalimide (NHPI) combined with was transition metal salts.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.