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Alfa Aesar™ N-Hydroxyphthalimide, 98+%

$50.49 - $581.55

Chemical Identifiers

Chemical Name or Material N-Hydroxyphthalimide
CAS 524-38-9
Molecular Formula C8H5NO3
Formula Weight 163.13g/mol
MDL Number MFCD00005891
Beilstein 131208
Merck Index 14,4838
Synonym NHPI
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1386222

 
alfa aesar™
A13862-22
100g Each for $50.49

AAA138620E

 
alfa aesar™
A13862-0E
2500g Each for $581.55

AAA1386236

 
alfa aesar™
A13862-36
500g Each for $166.72
Description & Specifications

Specifications

Melting Point ≈233°C (dec.)
Quantity 100g
Chemical Name or Material N-Hydroxyphthalimide
CAS 524-38-9
Assay ≥98%
Molecular Formula C8H5NO3
Formula Weight 163.13g/mol
MDL Number MFCD00005891
Beilstein 131208
Merck Index 14,4838
Synonym NHPI
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
RTECS Number TI5200000
TSCA TSCA

Applications
Aerobic oxidation of various alcohols has been accomplished by using a new catalytic system, N-hydroxyphthalimide (NHPI) combined with Co (acac). A practical catalytic method to convert alkylbenzenes into the corresponding carboxylic acids under atmospheric dioxygen at ambient temperature using a combined catalytic system consisting of N-hydroxyphthalimide (NHPI) and Co (OAc) 2 was developed. Novel catalysis by N-hydroxyphthalimide in the oxidation of organic substrates by molecular oxygen was described. Free radical functionalization of organic compounds catalyzed by N-hydroxyphthalimide. Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions. Hydroxylation of polycyclic alkanes with molecular oxygen catalyzed by N-hydroxyphthalimide (NHPI) combined with was transition metal salts.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.