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Alfa Aesar™ N-Boc-D-phenylglycine, 99%

$60.28 - $191.22

Chemical Identifiers

CAS 33125-05-2
Molecular Formula C13H17NO4
Molecular Weight (g/mol) 251.282
MDL Number MFCD00062043
InChI Key HOBFSNNENNQQIU-SNVBAGLBSA-N
Synonym boc-d-phg-oh, boc-d-phenylglycine, n-boc-d-phenylglycine, n-boc-d-2-phenylglycine, n-boc-l-phenylglycine, n-tert-butoxycarbonyl-d-2-phenylglycine, boc-d-alpha-phenylglycine, r-tert-butoxycarbonyl amino phenyl acetic acid, r-tert-butoxycarbonylamino-phenyl-acetic acid, r-2-tert-butoxycarbonyl amino-2-phenylacetic acid
PubChem CID 2755953
IUPAC Name (2R)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-phenylacetic acid
SMILES CC(C)(C)OC(=O)NC(C1=CC=CC=C1)C(=O)O
View More Specs

Products 2
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL1854003 View Documents Alfa Aesar™
L1854003
1g Each for $60.28
 
AAL1854006 View Documents Alfa Aesar™
L1854006
5g Each for $191.22
 
Description

Description

Applications
It is a reagent of choice for assignment of absolute configuration of chiral primary amines by 1H NMR, giving better results than Mosher′s acid ((R)-(+)-ɑ-Methoxy-ɑ-(trifluoromethyl)­phenyl­acetic acid. αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is D-(+)-2-Phenylglycine with Boc protecting group. (αR)-α-[[(1,1-Dimethylethoxy)carbonyl]amino]-benzeneacetic Acid is used as part of a catalyst combination to catalyze regioselective [4 + 2] cycloadditions of β-substituted cyclic enones and polyconjugated malononitriles. It can also be used to catalyze stereoselective preparation of polyfunctional nitrocyclohexene carboxaldehydes.

Solubility
Insoluble in water. Slightly soluble in DMSO and methanol.

Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications

Chemical Identifiers

33125-05-2
251.282
HOBFSNNENNQQIU-SNVBAGLBSA-N
2755953
CC(C)(C)OC(=O)NC(C1=CC=CC=C1)C(=O)O
C13H17NO4
MFCD00062043
boc-d-phg-oh, boc-d-phenylglycine, n-boc-d-phenylglycine, n-boc-d-2-phenylglycine, n-boc-l-phenylglycine, n-tert-butoxycarbonyl-d-2-phenylglycine, boc-d-alpha-phenylglycine, r-tert-butoxycarbonyl amino phenyl acetic acid, r-tert-butoxycarbonylamino-phenyl-acetic acid, r-2-tert-butoxycarbonyl amino-2-phenylacetic acid
(2R)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-phenylacetic acid

Specifications

−144° (c=1 in Ethanol)
1g
C13H17NO4
3033982
HOBFSNNENNQQIU-SNVBAGLBSA-N
(2R)-2-[(2-methylpropan-2-yl)oxycarbonylamino]-2-phenylacetic acid
2755953
99%
90°C to 92°C
33125-05-2
MFCD00062043
boc-d-phg-oh, boc-d-phenylglycine, n-boc-d-phenylglycine, n-boc-d-2-phenylglycine, n-boc-l-phenylglycine, n-tert-butoxycarbonyl-d-2-phenylglycine, boc-d-alpha-phenylglycine, r-tert-butoxycarbonyl amino phenyl acetic acid, r-tert-butoxycarbonylamino-phenyl-acetic acid, r-2-tert-butoxycarbonyl amino-2-phenylacetic acid
CC(C)(C)OC(=O)NC(C1=CC=CC=C1)C(=O)O
251.282
251.28
N-Boc-D-phenylglycine
Safety and Handling

Safety and Handling

Recommended Storage : 2° to 8°C