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mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene, Thermo Scientific Chemicals
$127.37 - $504.42
Chemical Identifiers
| CAS | 67719-69-1 |
|---|---|
| Molecular Formula | C13H18AlClTi |
| MDL Number | MFCD00151575 |
| Synonym | Tebbe Reagent |
Description
μ-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 67719-69-1 | |
| C13H18AlClTi | |
| MFCD00151575 | |
| Tebbe Reagent |
Specifications
| 67719-69-1 | |
| 0.927 g/mL | |
| C13H18AlClTi | |
| 5 mL | |
| Air and moisture sensitive | |
| Tebbe Reagent | |
| 284.62 | |
| mu-Chloro-mu-methylenebis (cyclopentadienyl)titaniumdimethylaluminum |
| Brown-Red | |
| 1°C (34°F) | |
| MFCD00151575 | |
| UN3399 | |
| 14,9091 | |
| Soluble in toluene,benzene,dichloromethane. Insoluble in water. | |
| Liquid |
Safety and Handling
GHS H Statement
H225-H261-H304-H361-H373-H314-H336
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.
P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
H225-H304-H314-H335-H336-H361d-H373
DOTInformation : Hazard Class: 3; Packaging Group: II
TSCA : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only