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Alfa Aesar™ Methyl nitroacetate, 98%

$88.00 - $295.03

Chemical Identifiers

Chemical Name or Material Methyl nitroacetate
CAS 2483-57-0
Molecular Formula C3H5NO4
Linear Formula O2NCH2CO2CH3
Formula Weight 119.08g/mol
MDL Number MFCD00075480
Beilstein 1758670
Synonym Nitroacetic acid methyl ester
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1895004

 
alfa aesar™
L18950-04
2g Each for $88.00

AAL1895009

 
alfa aesar™
L18950-09
10g Each for $295.03
Description & Specifications

Specifications

Boiling Point 195° to 198°C
Quantity 2g
Flash Point 105°C (221°F)
Odor Ester-like
Chemical Name or Material Methyl nitroacetate
CAS 2483-57-0
Assay 98%
Molecular Formula C3H5NO4
Linear Formula O2NCH2CO2CH3
Formula Weight 119.08g/mol
MDL Number MFCD00075480
Beilstein 1758670
Synonym Nitroacetic acid methyl ester
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319
Causes skin irritation.
Causes serious eye irritation.
Health Hazard 3 GHS P Statement
P280g-P305+P351+P338
Wear protective gloves.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
RTECS Number AJ1093000

Applications
Methyl nitroacetate is used in the synthesis of aromatic and heteroaromatic linear (E)-alfa-nitro-arylpentenoates. It is also used to prepare phenyliodonium ylide. Further, it is utilized in the highly enantioselective and diastereoselective copper(I)-catalyzed cyclopropanation of alkenes. In addition to this, it is employed in the production of methyl (Z)-2-nitro-3-(4-nitrophenyl)-2-propenoate through reaction with 4-nitrobenzylideneaniline.

Solubility
Miscible with ethanol, ether and most organic solvents.

Notes
Light sensitive. Incompatible withstrong bases.

Safety and Handling

Warning

GHS P Statement
P280g-P305+P351+P338
Wear protective gloves.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

GHS H Statement
H315-H319
Causes skin irritation.
Causes serious eye irritation.