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Methyl hydrogen malonate, 96%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals H2777206

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Catalog No. AAH2777206



Description

Description

Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Specifications

Specifications

Methyl hydrogen malonate
1.128
1.4295
5 g
PBVZQAXFSQKDKK-UHFFFAOYSA-N
3-methoxy-3-oxopropanoic acid
538366
96%
16695-14-0
C4H6O4
MFCD00667796
methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate
COC(=O)CC(=O)O
118.088
118.09

Chemical Identifiers

16695-14-0
118.088
PBVZQAXFSQKDKK-UHFFFAOYSA-N
538366
COC(=O)CC(=O)O
C4H6O4
MFCD00667796
methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate
3-methoxy-3-oxopropanoic acid
Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

TSCA : No

Recommended Storage : Keep cold

SDS
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