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Methyl hydrogen malonate, 96%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals H2777206
Description
Lactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsLactonization of olefins with monomethyl ester of malonic acid and ceric ammonium nitrate was carried out in acetic acid and in acetonitrile under simple mechanical stirring or ultrasound irradiation. Lactonization of olefins with CAN and monomethyl ester of malonic acid under ultrasound irradiation shows an acceleration with respect to the analogous mechanically stirred reaction.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Specifications
Methyl hydrogen malonate | |
1.128 | |
1.4295 | |
5 g | |
PBVZQAXFSQKDKK-UHFFFAOYSA-N | |
3-methoxy-3-oxopropanoic acid | |
538366 | |
96% |
16695-14-0 | |
C4H6O4 | |
MFCD00667796 | |
methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate | |
COC(=O)CC(=O)O | |
118.088 | |
118.09 |
Chemical Identifiers
16695-14-0 | |
118.088 | |
PBVZQAXFSQKDKK-UHFFFAOYSA-N | |
538366 | |
COC(=O)CC(=O)O |
C4H6O4 | |
MFCD00667796 | |
methyl hydrogen malonate, malonic acid monomethyl ester, 3-methoxy-3-oxo-propanoic acid, 1-methyl malonate, hydrogen methyl malonate | |
3-methoxy-3-oxopropanoic acid |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
TSCA : No
Recommended Storage : Keep cold
RUO – Research Use Only