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Methyl crotonate, 96%, trans-isomer, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals A1536336
Description
Methyl crotonate was used to investigate chemo selectivity in the reaction between methyl crotonate and benzyl amine catalyzed by lipase B from Candida Antarctica using solvent engineering. It was used as starting reagent during the total synthesis of phytotoxins solanapyrones D(1) and E(2).
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsMethyl crotonate was used to investigate chemo selectivity in the reaction between methyl crotonate and benzyl amine catalyzed by lipase B from Candida Antarctica using solvent engineering. It was used as starting reagent during the total synthesis of phytotoxins solanapyrones D(1) and E(2).
Solubility
Insoluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agents.
Specifications
| Methyl crotonate | |
| 0.946 | |
| 4°C (40°F) | |
| 1.4255 | |
| 500 g | |
| 1720292 | |
| methyl crotonate, e-methyl but-2-enoate, trans-methyl crotonate, methyl e-crotonate, methyl 2-butenoate, methyl trans-crotonate, 2-butenoic acid, methyl ester, 2e, trans-2-butenoic acid methyl ester, methyl trans-2-butenoate, e-crotonic acid methyl ester | |
| MCVVUJPXSBQTRZ-ONEGZZNKSA-N | |
| methyl (E)-but-2-enoate | |
| 638132 | |
| 98% |
| 623-43-8 | |
| 118°C to 120°C | |
| C5H8O2 | |
| MFCD00009287 | |
| UN3272 | |
| 14,2597 | |
| Insoluble in water. | |
| COC(=O)\C=C\C | |
| 100.12 | |
| 100.12 |
Chemical Identifiers
| 623-43-8 | |
| 100.12 | |
| MCVVUJPXSBQTRZ-ONEGZZNKSA-N | |
| 638132 | |
| COC(=O)\C=C\C |
| C5H8O2 | |
| MFCD00009287 | |
| methyl crotonate, e-methyl but-2-enoate, trans-methyl crotonate, methyl e-crotonate, methyl 2-butenoate, methyl trans-crotonate, 2-butenoic acid, methyl ester, 2e, trans-2-butenoic acid methyl ester, methyl trans-2-butenoate, e-crotonic acid methyl ester | |
| methyl (E)-but-2-enoate |
Safety and Handling
GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P240-P241-P242-P243-P264b-P280-P303+P361+P353-P305+P351+P338-P370+P378q-P501c
H225-H319
DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: ESTERS, N.O.S.
EINECSNumber : 210-793-7
RTECSNumber : GQ5710000
TSCA : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only