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m-Anisidine, 98%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A108150B

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Catalog No. AAA108150B



Description

Description

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Solubility
Soluble in water(18g/L).

Notes
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
Specifications

Specifications

m-Anisidine
-1°C
250°C to 251°C
Characteristic
1.581
1000 g
386119
14,667
Soluble in water(18g/L).
COC1=CC=CC(=C1)N
123.155
123.16
536-90-3
1.101
126°C (258°F)
C7H9NO
MFCD00007783
UN2431
Light sensitive
m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i
NCBZRJODKRCREW-UHFFFAOYSA-N
3-methoxyaniline
10824
98%

Chemical Identifiers

536-90-3
123.155
NCBZRJODKRCREW-UHFFFAOYSA-N
10824
COC1=CC=CC(=C1)N
C7H9NO
MFCD00007783
m-anisidine, 3-aminoanisole, m-methoxyaniline, 3-methoxybenzenamine, 3-anisidine, m-aminoanisole, benzenamine, 3-methoxy, m-anisylamine, 1-amino-3-methoxybenzene, unii-jxa144kx2i
3-methoxyaniline
Safety and Handling

Safety and Handling

GHS H Statement
H311-H373-H302-H332
Toxic in contact with skin.
May cause damage to organs through prolonged or repeated exposure.
Harmful if swallowed.
Harmful if inhaled.

P260-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P314-P330-P361-P363-P501c

H302+H332-H311-H373

DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ANISIDINES

EINECSNumber : 208-651-4

RTECSNumber : BZ5408000

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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