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Alfa Aesar™ Lithium amide, 95%

Chemical Identifiers

Chemical Name or Material Lithium amide
CAS 7782-89-0
Molecular Formula H2LiN
Linear Formula LiNH2
Formula Weight 22.96g/mol
MDL Number MFCD00011093
UN Number UN1390
Merck Index 14,5522
Synonym Lithamide
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1602314

 
alfa aesar™
L16023-14
25g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAL1602322

 
alfa aesar™
L16023-22
100g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAL1602336

 
alfa aesar™
L16023-36
500g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Melting Point 373°C
Boiling Point 430°C
Quantity 25g
Chemical Name or Material Lithium amide
CAS 7782-89-0
Assay 95%
Molecular Formula H2LiN
Linear Formula LiNH2
Formula Weight 22.96g/mol
MDL Number MFCD00011093
UN Number UN1390
Merck Index 14,5522
Synonym Lithamide
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H261-H314-H318
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3 GHS P Statement
P280-P305+P351+P338-P309-P310-P370+P378m-P402
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
In case of fire: Use for extinction: Limestone powder.
Store in a dry place.
DOT Information Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ALKALI METAL AMIDES
RTECS Number OJ5590000
TSCA TSCA

Applications
Lithium amide is used in the preparation of active pharmaceutical ingredients and antioxidants. It acts as a catalyst for polymers, as nucleophiles and as strong bases. It serves as a reagent in the synthesis of antiinflamatory and preoresolving protectin D1, chemotype dipeptidyl peptidase IV inhibitors and sterically congested triarylamines. It finds application in dyes displaying large stokes shifts. In addition to this, it is used as a reagent for cross-coupling of aryl chlorides and amine.

Solubility
Slightly soluble in ethanol and liquid ammonia. Insoluble in anhydrous ether, benzene and toluene.

Notes
Moisture sensitive. Incompatible with strong oxidizing agents, acids, water and alcohols.

Safety and Handling

Danger

GHS P Statement
P280-P305+P351+P338-P309-P310-P370+P378m-P402
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
In case of fire: Use for extinction: Limestone powder.
Store in a dry place.

GHS H Statement
H261-H314-H318
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.