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Alfa Aesar™ Lead(IV) acetate, 96% (dry wt.), stab. with 5-10% glacial acetic acid

Manufacturer:  Alfa Aesar™ A1555130

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Catalog No. AAA1555130



Description

Description

Applications
Lead(IV) acetate is an important oxidizing agent and a source of acetyloxy group used in organic synthesis. For example, 1,4-dioxene is prepared from dioxane involving 2-acetoxy-1,4-dioxane as an intermediate. Similarly, it is used for the preparation of bis(trifluoromethyl)diazomethane from hexafluoroacetone hydrazone. It also reacts with alkenes, alcohols having a delta-proton and di-n-butyl d-tartrate to get gamma-lactones, cyclic ethers and n-butyl glyoxylate respectively. It induces the cleavage of 1,2-diols to the corresponding aldehydes or ketones. It is actively involved in the Kochi reaction for the decarboxylation of carboxylic acids to alkyl halides and used as an alternative reagent to bromine in the Hofmann rearrangement.

Solubility
Soluble in water, ethanol, chloroform, benzene, nitrobenzene, tetrachloroethane, nitric acid, hot acetic acid and hydrochloric acid.

Notes
Air and moisture sensitive. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with alcohols, strong acids and strong reducing agents.
Specifications

Specifications

Lead(IV) acetate
stabilized with 5 to 10% glacial acetic acid
546-67-8
C8H16O8Pb
MFCD00008693
3595640
lead iv acetate
CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Pb]
447.408
443.37
175°C
250g
(dry wt.)
Pb(OOCCH3)4
UN1616
14,5423
NVTAREBLATURGT-UHFFFAOYSA-N
acetic acid;lead
50931538
96%

Chemical Identifiers

546-67-8
447.408
NVTAREBLATURGT-UHFFFAOYSA-N
50931538
CC(=O)O.CC(=O)O.CC(=O)O.CC(=O)O.[Pb]
C8H16O8Pb
MFCD00008693
lead iv acetate
acetic acid;lead
Safety and Handling

Safety and Handling

GHS H Statement
H360-H373-H302-H332-H201
May damage fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Harmful if swallowed.
Harmful if inhaled.
Explosive; mass explosion hazard.

GHS P Statement
P260-P261-P281-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use personal protective equipment as required.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: LEAD ACETATE

RTECSNumber : AI5300000

TSCA : TSCA

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