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Alfa Aesar™ Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF

Chemical Identifiers

CAS 807329-97-1
Molecular Formula C3H7ClMg·LiCl
Linear Formula (CH3)2CHMgCl·LiCl
Formula Weight 145.24
MDL Number MFCD07784514
UN Number UN3399
Chemical Name or Material Isopropylmagnesium chloride - LiCl complex
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAH51156AE SDS Alfa Aesar™
H51156AE
100mL N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
AAH51156AP SDS Alfa Aesar™
H51156AP
500mL N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Specifications

Description

Applications
Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Solubility
Miscible with ethers and amines.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents and water.
Description & Specifications

Chemical Identifiers

807329-97-1
(CH3)2CHMgCl·LiCl
MFCD07784514
Isopropylmagnesium chloride - LiCl complex
C3H7ClMg·LiCl
145.24
UN3399

Specifications

1M in MeTHF
100mL
C3H7ClMg·LiCl
145.24
UN3399
−17°C (1.4°F)
807329-97-1
(CH3)2CHMgCl·LiCl
MFCD07784514
Isopropylmagnesium chloride - LiCl complex

Safety and Handling

GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.

GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE