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Alfa Aesar™ Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF

Chemical Identifiers

Chemical Name or Material Isopropylmagnesium chloride - LiCl complex
CAS 807329-97-1
Molecular Formula C3H7ClMg·LiCl
Linear Formula (CH3)2CHMgCl·LiCl
Formula Weight 145.24
MDL Number MFCD07784514
UN Number UN3399
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAH51156AE

  SDS
alfa aesar™
H51156AE
100mL CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAH51156AP

  SDS
alfa aesar™
H51156AP
500mL CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Formula Weight 145.24
Chemical Name or Material Isopropylmagnesium chloride - LiCl complex
Molecular Formula C3H7ClMg·LiCl
Linear Formula (CH3)2CHMgCl·LiCl
MDL Number MFCD07784514
CAS 807329-97-1
UN Number UN3399
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3 GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
Concentration 1M in MeTHF
Flash Point −17°C (1.4°F)
Quantity 100mL

Applications
Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Solubility
Miscible with ethers and amines.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents and water.

Safety and Handling

Danger

GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.