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Iodosobenzene diacetate, 98+%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals B2453136

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Catalog No. AAB2453136



Description

Description

Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Iodosobenzene is used as an oxidizing and acetoxylating agent in organic synthesis. It is actively involved in the preparation of (Z)-3,7-dimethyl-2,6-octadien-1-al(neral) from (Z)-3,7-dimethyl-2,6-octadien-1-ol (nerol) in presence of 2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO). It is a useful reagent for the synthesis of a wide variety of heterocyclic compounds. It is also used in the Pd-catalyzed 2-arylation of indoles.

Solubility
Insoluble in water.

Notes
Light sensitive. Incompatible with strong oxidizing agents.
Specifications

Specifications

Iodosobenzene diacetate
159°C to 161°C
MFCD00008692
1879369
iodobenzene diacetate, diacetoxyiodo benzene, iodosobenzene diacetate, phenyliodine diacetate, phenyliodo diacetate, phenyliodoso acetate, phenyliodosodiacetate, phenyliodoso diacetate, bis acetato phenyliodine, benzene, diacetoxyiodo
ZBIKORITPGTTGI-UHFFFAOYSA-N
[acetyloxy(phenyl)-$l^{3}-iodanyl] acetate
76724
≥98%
3240-34-4
C10H11IO4
500 g
Light sensitive
Insoluble in water.
CC(=O)OI(C1=CC=CC=C1)OC(=O)C
322.098
322.1

Chemical Identifiers

3240-34-4
322.098
ZBIKORITPGTTGI-UHFFFAOYSA-N
76724
CC(=O)OI(C1=CC=CC=C1)OC(=O)C
C10H11IO4
MFCD00008692
iodobenzene diacetate, diacetoxyiodo benzene, iodosobenzene diacetate, phenyliodine diacetate, phenyliodo diacetate, phenyliodoso acetate, phenyliodosodiacetate, phenyliodoso diacetate, bis acetato phenyliodine, benzene, diacetoxyiodo
[acetyloxy(phenyl)-$l^{3}-iodanyl] acetate
Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

H302+H312-H315-H319-H335

EINECSNumber : 221-808-1

RTECSNumber : DA3525000

TSCA : Yes

Recommended Storage : Ambient temperatures

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