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Hexamethylphosphorous triamide, 97%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A1257106

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Catalog No. AAA1257106



Description

Description

Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Hexamethylphosphorous triamide is used as a reagent in organic synthesis as a phosphorylating agent. It is associated with carbon tetrachloride for the substitution of hydroxy groups with chlorides. It is involved in the preparation of epoxides and arene oxides from aldehydes and aryldialdehdyes respectively. It is used in the preparation of carbonates as well as reduction of ozonides.

Solubility
Miscible with water.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
Specifications

Specifications

Hexamethylphosphorous triamide
-44°C
162°C to 164°C
C6H18N3P
MFCD00008301
UN1993
Air sensitive; May form a precipitate
Miscible with water.
CN(C)P(N(C)C)N(C)C
163.21
163.21
1608-26-0
0.898
37°C (98°F)
1.465
5 g
906778
hexamethylphosphorous triamide, tris dimethylamino phosphine, hexametapil, phosphorous triamide, hexamethyl, hexamethyltriamidophosphite, hexamethyltriaminophosphine, phosphine, tris dimethylamino, bis dimethylamino phosphanyl dimethylamine, hmpt van, hexamethyl phosphorus triamide
XVDBWWRIXBMVJV-UHFFFAOYSA-N
N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine
15355
97%

Chemical Identifiers

1608-26-0
163.21
XVDBWWRIXBMVJV-UHFFFAOYSA-N
15355
CN(C)P(N(C)C)N(C)C
C6H18N3P
MFCD00008301
hexamethylphosphorous triamide, tris dimethylamino phosphine, hexametapil, phosphorous triamide, hexamethyl, hexamethyltriamidophosphite, hexamethyltriaminophosphine, phosphine, tris dimethylamino, bis dimethylamino phosphanyl dimethylamine, hmpt van, hexamethyl phosphorus triamide
N-[bis(dimethylamino)phosphanyl]-N-methylmethanamine
Safety and Handling

Safety and Handling

GHS H Statement
H340-H350-H226
May cause genetic defects.
May cause cancer.
Flammable liquid and vapour.

P201-P202-P210-P233-P240-P243-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P308+P313-P332+P313-P362-P374-P380-P501c

H226-H315-H319-H335-H351

DOTInformation : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.

EINECSNumber : 216-534-4

RTECSNumber : TH3390000

TSCA : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

SDS
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RUO – Research Use Only