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Alfa Aesar™ Ethyltriphenylphosphonium bromide, 98+%

Chemical Identifiers

Chemical Name or Material Ethyltriphenylphosphonium bromide
CAS 1530-32-1
Molecular Formula C20H20BrP
Linear Formula CH3CH2P(C6H5)3Br
Formula Weight 371.26
MDL Number MFCD00011838
UN Number UN3077
Beilstein 3599630
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Products
Catalog Number Mfr. No. Packaging Quantity Price Quantity    

AAB2309614

  SDS
alfa aesar™
B2309614
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 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAB2309622

  SDS
alfa aesar™
B2309622
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 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAB2309636

  SDS
alfa aesar™
B2309636
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Description & Specifications

Specifications

Formula Weight 371.26
Chemical Name or Material Ethyltriphenylphosphonium bromide
TSCA TSCA
Assay ≥98%
Molecular Formula C20H20BrP
Linear Formula CH3CH2P(C6H5)3Br
MDL Number MFCD00011838
CAS 1530-32-1
UN Number UN3077
Beilstein 3599630
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H302-H312-H315-H319-H335
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Melting Point 206° to 210°C
Odor Odorless
Quantity 25g
Flash Point >200°C (392°F)
DOT Information Transport Hazard Class: 9; Packing Group: III; Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, SOLID, N.O.S.

Applications
Ethyltriphenylphosphonium bromide acts as a reactant in the synthesis of D-amino acids from L-cysteine-derived thiazolidines, Leiodolide A through aldol reactions and Horner-Wadsworth-Emmons olefination. It is also used in the preparation of cycloalkanoindolines through diastereoselective intramolecular inimo-ene reactions. Further, it is used as a reagent in solid-state metathesis polycondensation to prepare alkyl-dipropenylthiophene monomers and Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization reactions.

Solubility
Soluble in methanol. Slightly soluble in water, acetone and isopropanol.

Notes
Hygroscopic. Incompatible with oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H302-H312-H315-H319-H335
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.