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Alfa Aesar™ Ethoxyacetylene, ca 50% w/w in hexanes

$120.22 - $120.22

Chemical Identifiers

Chemical Name or Material Ethoxyacetylene
CAS 927-80-0
Molecular Formula C4H6O
Linear Formula CH3CH2OC≡CH
Formula Weight 70.09g/mol
MDL Number MFCD00009247
UN Number UN1993
Beilstein 741882
Synonym Ethyl ethynyl ether
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1424506

 
alfa aesar™
A14245-06
5g Each for $120.22

AAA1424503

 
alfa aesar™
A14245-03
1g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAA1424514

 
alfa aesar™
A14245-14
25g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Boiling Point 55° to 56°C
Odor Recognizable
Concentration ≈50% w/w in hexanes
Quantity 5g
Flash Point −28°C (−18°F)
Chemical Name or Material Ethoxyacetylene
CAS 927-80-0
Molecular Formula C4H6O
Linear Formula CH3CH2OC≡CH
Formula Weight 70.09g/mol
MDL Number MFCD00009247
UN Number UN1993
Beilstein 741882
Synonym Ethyl ethynyl ether
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H225-H304-H361-H373-H315
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes skin irritation.
Health Hazard 3 GHS P Statement
P210-P280h-P281-P301+P330+P331-P315-P403+P235
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Wear protective gloves/clothing.
Use personal protective equipment as required.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Get immediate medical advice/attention.
Store in a well-ventilated place. Keep cool.
Recommended Storage 2° to 8°C
DOT Information Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
RTECS Number KN9900000

Applications
Ethoxyacetylene is used in Arens-van Dorp synthesis to prepare propargyl alcohol via reaction with ketone. In organic synthesis, it undergoes [2+2] cycloaddition reactions with ketenes to give cyclobutenone derivatives. It is also used to prepare alpha, beta-unsaturated esters from ketones by following Meyer-Schuster rearrangement.Used with N-vinylamides and triflic anhydride in a direct, three-component synthesis of pyridines. Also used to prepare α, β-unsaturated esters from ketones via a Meyer-Schuster rearrangement.

Solubility
Slightly miscible with water.

Notes
Incompatible with strong oxidizing agents and strong acids.

Safety and Handling

Danger

GHS P Statement
P210-P280h-P281-P301+P330+P331-P315-P403+P235
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Wear protective gloves/clothing.
Use personal protective equipment as required.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Get immediate medical advice/attention.
Store in a well-ventilated place. Keep cool.

GHS H Statement
H225-H304-H361-H373-H315
Highly flammable liquid and vapour.
May be fatal if swallowed and enters airways.
Suspected of damaging fertility or the unborn child.
May cause damage to organs through prolonged or repeated exposure.
Causes skin irritation.

2° to 8°C