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Diiodomethane, 99%, stab., Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A1545714

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Catalog No. AAA1545714



Description

Description

Diiodomethane is used to determine the density of minerals and other solid samples due to its high density. It is used as an optical contact liquid to determine the refractive index of certain gemstones. In simmons-smith reaction, it acts as a reagent to generate methylene (carbine) free radical. It reacts with olefins to prepare cyclopropanes with high stereo specificity.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Diiodomethane is used to determine the density of minerals and other solid samples due to its high density. It is used as an optical contact liquid to determine the refractive index of certain gemstones. In simmons-smith reaction, it acts as a reagent to generate methylene (carbine) free radical. It reacts with olefins to prepare cyclopropanes with high stereo specificity.

Solubility
Miscible with alcohol and ether. Slightly miscible with water.

Notes
Light sensitive. Keep container tightly closed in a dry and well-ventilated place. Incompatible with alkali metal salts, strong oxidizing agents, strong bases, metals, lithium, potassium, sodium, sodium oxides and alloys.
Specifications

Specifications

Diiodomethane
75-11-6
3.322
None
CH2I2
MFCD00001079
UN2810
Light sensitive
methylene iodide, methane, diiodo, methylene diiodide, mi-gee, dijodmethan, methylenjodid, dijodmethan czech, methylenjodid czech, di-iodomethane, diiodo-methane
NZZFYRREKKOMAT-UHFFFAOYSA-N
diiodomethane
6346
99%
stabilized
5°C to 6°C
180°C to 181°C (decomposition)
99%, stab.
1.74
25 g
1696892
14,6066
Miscible with alcohol and ether. Slightly miscible with water.
ICI
267.84
267.84
Liquid

Chemical Identifiers

75-11-6
267.84
NZZFYRREKKOMAT-UHFFFAOYSA-N
6346
ICI
CH2I2
MFCD00001079
methylene iodide, methane, diiodo, methylene diiodide, mi-gee, dijodmethan, methylenjodid, dijodmethan czech, methylenjodid czech, di-iodomethane, diiodo-methane
diiodomethane
Safety and Handling

Safety and Handling

GHS H Statement
H302-H332-H315-H319-H335
Harmful if swallowed.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P305+P351+P338-P310-P312-P330-P332+P313-P362-P501c

H301-H315-H318-H335

DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC, LIQUIDS, ORGANIC, N.O.S.

EINECSNumber : 200-841-5

RTECSNumber : PA8575000

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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