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Alfa Aesar™ (+)-Diethyl L-tartrate, 98%

$57.57 - $369.16

Chemical Identifiers

Chemical Name or Material (+)-Diethyl L-tartrate
CAS 87-91-2
Molecular Formula C8H14O6
Formula Weight 206.19
MDL Number MFCD00009143
Beilstein 1727145
Merck Index 14,3855
Synonym L-Tartaric acid diethyl ester
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1064122

  SDS
alfa aesar™
A1064122
100g Each for $57.57

AAA106410B

  SDS
alfa aesar™
A106410B
1000g Each for $369.16

AAA1064130

  SDS
alfa aesar™
A1064130
250g Each for $127.01

AAA1064136

  SDS
alfa aesar™
A1064136
500g Each for $227.53
Description & Specifications

Specifications

Formula Weight 206.19
Health Hazard 3 GHS P Statement
P210-P280-P370+P378a-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Wear protective gloves/protective clothing/eye protection/face protection.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place.
Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Boiling Point 280°C
TSCA TSCA
Health Hazard 2 GHS H Statement
H227
Combustible liquid.
Chemical Name or Material (+)-Diethyl L-tartrate
Beilstein 1727145
Melting Point 17°C
MDL Number MFCD00009143
Assay 98%
CAS 87-91-2
Synonym L-Tartaric acid diethyl ester
Molecular Formula C8H14O6
Flash Point 93°C (199°F)
Optical Rotation +27° (c=1 in water)
Merck Index 14,3855
Health Hazard 1 Warning
Quantity 100g

Applications
(+)-Diethyl L-tartrate is used as a chiral auxiliary in the Sharpless enantioselective epoxidation of allylic alcohols, for Sharpless-type enantioselective oxidation of sulfides to sulfoxides and as a chiral auxiliary in the enantioselective construction of cyclopropanes from allylic alcohols by an asymmetric Simmons-Smith reaction. It is also used as a chiral reagent in a host of chemical reactions, such as the synthesis of isoquinoline alkaloids and arundic acid, which has been used in acute ischemic stroke therapy.

Solubility
Fully miscible in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P210-P280-P370+P378a-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Wear protective gloves/protective clothing/eye protection/face protection.
In case of fire: Use for extinction: CO2, powder or water spray.
Store in a well-ventilated place.
Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H227
Combustible liquid.