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Alfa Aesar™ Diethyl ethoxymethylenemalonate, 98+%

$26.50 - $215.01

Chemical Identifiers

Chemical Name or Material Diethyl ethoxymethylenemalonate
CAS 87-13-8
Molecular Formula C10H16O5
Formula Weight 216.23g/mol
MDL Number MFCD00009148
Beilstein 880058
Synonym Ethoxymethylenemalonic acid diethyl ester; Ethoxymethylenepropanedioic acid diethyl ester
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA137760B

 
alfa aesar™
A13776-0B
1000g Each for $215.01

AAA1377618

 
alfa aesar™
A13776-18
50g Each for $26.50

AAA1377622

 
alfa aesar™
A13776-22
100g Each for $38.23

AAA1377630

 
alfa aesar™
A13776-30
250g Each for $54.91

AAA1377636

 
alfa aesar™
A13776-36
500g Each for $114.72
Description & Specifications

Specifications

Odor Ester-like
Boiling Point 136° to 139°C (10mmHg)
Melting Point −33°C
Flash Point 144°C (291°F)
Quantity 1000g
Chemical Name or Material Diethyl ethoxymethylenemalonate
CAS 87-13-8
Assay ≥98%
Molecular Formula C10H16O5
Formula Weight 216.23g/mol
MDL Number MFCD00009148
Beilstein 880058
Synonym Ethoxymethylenemalonic acid diethyl ester; Ethoxymethylenepropanedioic acid diethyl ester
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H334-H315-H319-H317
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Health Hazard 3 GHS P Statement
P284a-P261-P280-P305+P351+P338-P342+P311-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
Dispose of contents/container in accordance with local/regional/national/international regulations.
RTECS Number OO1100000
TSCA TSCA

Applications
Diethyl ethoxymethylenemalonate is used for synthesis of pyrido[3,2-e]pyrimido[1,2-c]pyrimidines. Initially, it was used to monitor lysine decarboxylase activity. It is useful in the determination of amino acids by precolumn derivatization by using reversed-phase high-performance liquid chromatography (HPLC). It plays an important role in the Gould-Jacobs reaction to prepare quinolines. For example, anile reacts with this reagent to give 4-hydroxyquinoline. It acts as an intermediate in the production of flumequine, which is a fluoroquinolone antibiotic.

Solubility
Miscible with chloroform, dichloromethane and methanol. Immiscible with water.

Notes
Incompatible with acids, bases, oxidizing agents and reducing agents.

Safety and Handling

Danger

GHS P Statement
P284a-P261-P280-P305+P351+P338-P342+P311-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H334-H315-H319-H317
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.