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Alfa Aesar™ Diethyl diallylmalonate, 98%

$1,194.49 - $1,194.49

Chemical Identifiers

Chemical Name or Material Diethyl diallylmalonate
CAS 3195-24-2
Molecular Formula C13H20O4
Formula Weight 240.3
MDL Number MFCD00009126
Beilstein 1790529
Synonym Diallylmalonic acid diethyl ester
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1246030

 
alfa aesar™
A1246030
250g Each for $1,194.49
Description & Specifications

Specifications

Formula Weight 240.3
Chemical Name or Material Diethyl diallylmalonate
Assay 98%
Molecular Formula C13H20O4
MDL Number MFCD00009126
CAS 3195-24-2
Boiling Point 242° to 244°C
Beilstein 1790529
Flash Point >110°C (230°F)
Synonym Diallylmalonic acid diethyl ester
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Quantity 250g

Applications
Diethyl diallylmalonate is the starting material for enantioselective synthesis of carbocyclic nucleoside analogues. It is also used as Low catalyst loading in ring-closing metathesis reaction. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

Solubility
Sparingly Soluble in water. (0.72 g/L) (25°C)

Notes
Store under cool dry place. Ensure good ventilation.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.