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Alfa Aesar™ Diethyl azodicarboxylate, 97%

$49.57 - $137.77

Chemical Identifiers

CAS 1972-28-7
Molecular Formula C6H10N2O4
Linear Formula CH3CH2O2C-N=N-CO2CH2CH3
Formula Weight 174.16
MDL Number MFCD00009103
UN Number UN2810
Beilstein 908662
Synonym Azodicarboxylic acid diethyl ester; DEAD
Chemical Name or Material Diethyl azodicarboxylate
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL1934814 SDS Alfa Aesar™
L1934814
25g Each for $137.77
AAL1934806 SDS Alfa Aesar™
L1934806
5g Each for $49.57
AAL1934822 SDS Alfa Aesar™
L1934822
100g N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Specifications

Description

Applications
Diethyl azodicarboxylate acts as a dienophile used in Diels-Alder reactions. It is used as a reagent in alfa-thiocyanation of enolizable ketones with ammonium thiocyanate and annulation of N-protected imines. It acts as a reactant for the preparation of immunostimulants alfa-Galactosylceramides, bisubstrate inhibitors with molecular recognition at the active site of catechol-O-methyltransferase and aza-beta-lactams via NHC-catalyzed [2 + 2] cycloaddition with ketenes. It finds application in Mitsunobu reaction and used in the synthesis of pharmaceuticals like zidovudine and procarbazine. The presence of azo group in it is a Michael acceptor and used for the conversion of beta-ketoesters to the corresponding hydrazine derivatives in presence of copper(II) catalyst. Further, it is an efficient dehydrogenating agent, which is involved in the preparation of aldehydes, disulfides from alcohols and thiols respectively.

Solubility
Miscible with dichloromethane, diethyl ether and toluene.

Notes
Store in a cool place. Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.
Description & Specifications

Chemical Identifiers

1972-28-7
CH3CH2O2C-N=N-CO2CH2CH3
MFCD00009103
908662
Diethyl azodicarboxylate
C6H10N2O4
174.16
UN2810
Azodicarboxylic acid diethyl ester; DEAD

Specifications

25g
C6H10N2O4
174.16
UN2810
908662
Azodicarboxylic acid diethyl ester; DEAD
97%
1972-28-7
CH3CH2O2C-N=N-CO2CH2CH3
MFCD00009103
106°C (13mmHg)
85°C (185°F)
Diethyl azodicarboxylate

Safety and Handling

GHS H Statement
H302-H312-H315-H319-H335-H227
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.

GHS P Statement
P210-P261-P280-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Warning

DOTInformation : Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC, LIQUIDS, ORGANIC, N.O.S.

Recommended Storage : 2° to 8°C