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Alfa Aesar™ Di-tert-butylchlorophosphine, 96%

$124.31 - $124.31

Chemical Identifiers

Chemical Name or Material Di-tert-butylchlorophosphine
CAS 13716-10-4
Molecular Formula C8H18ClP
Linear Formula [(CH3)3C]2PCl
Formula Weight 180.66
MDL Number MFCD00008815
UN Number UN3265
Synonym Chlorodi-tert-butylphosphine
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAB2099806

  SDS
alfa aesar™
B2099806
5g Each for $124.31

AAB2099814

  SDS
alfa aesar™
B2099814
25g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Formula Weight 180.66
MDL Number MFCD00008815
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Molecular Formula C8H18ClP
Flash Point 62°C (144°F)
CAS 13716-10-4
UN Number UN3265
Health Hazard 2 GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.
Boiling Point 47° to 49°C (3mmHg)
Synonym Chlorodi-tert-butylphosphine
Quantity 5g
Linear Formula [(CH3)3C]2PCl
Health Hazard 1 Danger
Chemical Name or Material Di-tert-butylchlorophosphine
Health Hazard 3 GHS P Statement
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
Odor Acrid
Assay 96%

Applications
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Miscible with terahydrofuran.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

Safety and Handling

Danger

GHS P Statement
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.