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Alfa Aesar™ Di-tert-butylchlorophosphine, 96%

$110.70 - $110.70

Chemical Identifiers

Chemical Name or Material Di-tert-butylchlorophosphine
CAS 13716-10-4
Molecular Formula C8H18ClP
Linear Formula [(CH3)3C]2PCl
Formula Weight 180.66g/mol
MDL Number MFCD00008815
UN Number UN3265
Synonym Chlorodi-tert-butylphosphine
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAB2099806

 
alfa aesar™
B20998-06
5g Each for $110.70

AAB2099803

 
alfa aesar™
B20998-03
1g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAB2099814

 
alfa aesar™
B20998-14
25g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Odor Acrid
Boiling Point 47° to 49°C (3mmHg)
Quantity 5g
Flash Point 62°C (144°F)
Chemical Name or Material Di-tert-butylchlorophosphine
CAS 13716-10-4
Assay 96%
Molecular Formula C8H18ClP
Linear Formula [(CH3)3C]2PCl
Formula Weight 180.66g/mol
MDL Number MFCD00008815
UN Number UN3265
Synonym Chlorodi-tert-butylphosphine
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.
Health Hazard 3 GHS P Statement
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Applications
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.

Solubility
Miscible with terahydrofuran.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents.

Safety and Handling

Danger

GHS P Statement
P280-P305+P351+P338-P309-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.