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Alfa Aesar™ Di-tert-butyl azodicarboxylate, 98%

$62.96 - $221.66

Chemical Identifiers

CAS 870-50-8
Molecular Formula (CH3)3CO2C-N=N-CO2C(CH3)3
Formula Weight 230.27
MDL Number MFCD00015001
Beilstein 1911434
Synonym Azodicarboxylic acid di-tert-butyl ester; DTAD
Chemical Name or Material Di-tert-butyl azodicarboxylate
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL0029406 SDS Alfa Aesar™
L0029406
5g Each for $62.96
AAL0029414 SDS Alfa Aesar™
L0029414
25g Each for $221.66
Specifications

Description

Applications
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates. It is also used in the electrophilic amination of beta-keto esters catalyzed by an axially chiral guanidine. It serves as a precursor in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such as L-proline or (S)-2-pyrrolidinyl tetrazole. It is also utilized in the asymmetric Friedel-Crafts amination through a chiral organocatalyst. Further, it acts as a reactant for preparation of hexapeptide key fragments through stereo selective selenocyclization/oxidative deselenylation reactions. In addition to this, it is employed as a starting material in the synthesis of pyrroloisoquinoline template through stereoselective N-acyliminium-mediated cyclization and enolate amination for preparation of peptidomimetic compounds and Barbier-type propargylation reactions.

Solubility
Soluble in most organic solvents. Insoluble in water.

Notes
Light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and alcohols.
Description & Specifications

Chemical Identifiers

870-50-8
230.27
1911434
Di-tert-butyl azodicarboxylate
(CH3)3CO2C-N=N-CO2C(CH3)3
MFCD00015001
Azodicarboxylic acid di-tert-butyl ester; DTAD

Specifications

89° to 92°C
870-50-8
230.27
1911434
Di-tert-butyl azodicarboxylate
5g
(CH3)3CO2C-N=N-CO2C(CH3)3
MFCD00015001
Azodicarboxylic acid di-tert-butyl ester; DTAD
98%

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Warning