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Alfa Aesar™ Di-tert-butyl azodicarboxylate, 98%

$72.57 - $248.03

Chemical Identifiers

CAS 870-50-8
Molecular Formula C10H18N2O4
Molecular Weight (g/mol) 230.264
MDL Number MFCD00015001
InChI Key QKSQWQOAUQFORH-VAWYXSNFSA-N
Synonym 1,2-diazenedicarboxylic acid, 1,2-bis 1,1-dimethylethyl ester, azodicarboxylic acid di-tert-butyl ester, di-tert-butyl azodicarboxylate, di-tert-butyl azodicarboxylate dbad, di-tert-butyl diazene-1,2-dicarboxylate, di-tert-butylazodicarboxylate, n-tert-butoxy carbonyl imino tert-butoxy formamide, n-tert-butoxycarbonyl imino tert-butoxy formamide, pubchem17548, tert-butyl tert-butyl oxycarbonyl diazenyl formate
PubChem CID 6034084
IUPAC Name tert-butyl (NE)-N-[(2-methylpropan-2-yl)oxycarbonylimino]carbamate
SMILES CC(C)(C)OC(=O)N=NC(=O)OC(C)(C)C
View More Specs

Products 2
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL0029406 View Documents Alfa Aesar™
L0029406
5g Each for $72.57
 
AAL0029414 View Documents Alfa Aesar™
L0029414
25g Each for $248.03
 
Description

Description

Applications
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates. It is also used in the electrophilic amination of beta-keto esters catalyzed by an axially chiral guanidine. It serves as a precursor in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such as L-proline or (S)-2-pyrrolidinyl tetrazole. It is also utilized in the asymmetric Friedel-Crafts amination through a chiral organocatalyst. Further, it acts as a reactant for preparation of hexapeptide key fragments through stereo selective selenocyclization/oxidative deselenylation reactions. In addition to this, it is employed as a starting material in the synthesis of pyrroloisoquinoline template through stereoselective N-acyliminium-mediated cyclization and enolate amination for preparation of peptidomimetic compounds and Barbier-type propargylation reactions.

Solubility
Soluble in most organic solvents. Insoluble in water.

Notes
Light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and alcohols.
Specifications

Chemical Identifiers

870-50-8
230.264
QKSQWQOAUQFORH-VAWYXSNFSA-N
6034084
CC(C)(C)OC(=O)N=NC(=O)OC(C)(C)C
C10H18N2O4
MFCD00015001
1,2-diazenedicarboxylic acid, 1,2-bis 1,1-dimethylethyl ester, azodicarboxylic acid di-tert-butyl ester, di-tert-butyl azodicarboxylate, di-tert-butyl azodicarboxylate dbad, di-tert-butyl diazene-1,2-dicarboxylate, di-tert-butylazodicarboxylate, n-tert-butoxy carbonyl imino tert-butoxy formamide, n-tert-butoxycarbonyl imino tert-butoxy formamide, pubchem17548, tert-butyl tert-butyl oxycarbonyl diazenyl formate
tert-butyl (NE)-N-[(2-methylpropan-2-yl)oxycarbonylimino]carbamate

Specifications

Light sensitive
5g
C10H18N2O4
1911434
Soluble in most organic solvents. Insoluble in water.
CC(C)(C)OC(=O)N=NC(=O)OC(C)(C)C
230.264
230.27
Di-tert-butyl azodicarboxylate
89°C to 92°C
870-50-8
MFCD00015001
1,2-diazenedicarboxylic acid, 1,2-bis 1,1-dimethylethyl ester, azodicarboxylic acid di-tert-butyl ester, di-tert-butyl azodicarboxylate, di-tert-butyl azodicarboxylate dbad, di-tert-butyl diazene-1,2-dicarboxylate, di-tert-butylazodicarboxylate, n-tert-butoxy carbonyl imino tert-butoxy formamide, n-tert-butoxycarbonyl imino tert-butoxy formamide, pubchem17548, tert-butyl tert-butyl oxycarbonyl diazenyl formate
QKSQWQOAUQFORH-VAWYXSNFSA-N
tert-butyl (NE)-N-[(2-methylpropan-2-yl)oxycarbonylimino]carbamate
6034084
98%
Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P210-P240-P241-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

H228-H315-H319-H335

DOTInformation : Hazard Class: 4.1; Packaging Group: III

EINECSNumber : 212-796-9

TSCA : No

Recommended Storage : Ambient temperatures