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Dess-Martin periodinane, Thermo Scientific Chemicals
$67.03 - $225.03
Chemical Identifiers
| CAS | 87413-09-0 |
|---|---|
| Molecular Formula | C13H13IO8 |
| Molecular Weight (g/mol) | 424.14 |
| MDL Number | MFCD00130127 |
| InChI Key | NKLCNNUWBJBICK-UHFFFAOYSA-N |
| PubChem CID | 159087 |
| SMILES | CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12 |
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|---|---|---|---|---|---|---|---|---|---|
| Catalog Number | Mfr. No. | Quantity | Price | Quantity | |||||
|
AAL1577903
|
Thermo Scientific Chemicals
L1577903 |
1 g |
N/A
|
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|
AAL1577906
|
Thermo Scientific Chemicals
L1577906 |
5 g |
N/A
|
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Description
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsDess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.
Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.
Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.
Chemical Identifiers
| 87413-09-0 | |
| 424.14 | |
| NKLCNNUWBJBICK-UHFFFAOYSA-N | |
| CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12 |
| C13H13IO8 | |
| MFCD00130127 | |
| 159087 |
Specifications
| 87413-09-0 | |
| C13H13IO8 | |
| 1 g | |
| 4548207 | |
| 14,2933 | |
| Soluble in chloroform,acetone,acetonitrile and methylene chloride. Slightly soluble in ether and hexane. | |
| CC(=O)O[I]1(OC(C)=O)(OC(C)=O)OC(=O)C2=CC=CC=C12 | |
| 424.14 | |
| 424.15 | |
| Dess-Martin periodinane |
| 130°C to 132°C (decomposition) | |
| MFCD00130127 | |
| UN1479 | |
| Air, light, and moisture sensitive | |
| dess-martin periodinane, triacetoxyperiodinane, 1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3 1h-one, dess-martin reagent, dess-martinperiodinane, dess-martin, dess martin periodinane, dess martin, dess-martin periodane | |
| NKLCNNUWBJBICK-UHFFFAOYSA-N | |
| (1,1-diacetyloxy-3-oxo-1$l^{5},2-benziodoxol-1-yl) acetate | |
| 159087 | |
| ≥95% |
Safety and Handling
GHS H Statement
H272-H315-H319-H335
May intensify fire; oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P220-P221-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c
H272-H315-H319-H335
DOTInformation : Transport Hazard Class: 5.1; Packing Group: III; Proper Shipping Name: OXIDIZING SOLID, N.O.S.
TSCA : No
Recommended Storage : Store at -20°C; Store under Argon
RUO – Research Use Only