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Alfa Aesar™ Dess-Martin periodinane

Chemical Identifiers

Chemical Name or Material Dess-Martin periodinane
CAS 87413-09-0
Molecular Formula C13H13IO8
Formula Weight 424.15
MDL Number MFCD00130127
UN Number UN1479
Beilstein 4548207
Merck Index 14,2933
Synonym DMP; 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1577903

  SDS
alfa aesar™
L1577903
1g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAL1577906

  SDS
alfa aesar™
L1577906
5g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Formula Weight 424.15
Molecular Formula C13H13IO8
Chemical Name or Material Dess-Martin periodinane
Beilstein 4548207
Recommended Storage −30° to −10°C
CAS 87413-09-0
UN Number UN1479
MDL Number MFCD00130127
Melting Point 130° to 132°C
Health Hazard 3 GHS P Statement
P221-P210-P220-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep/Store away from clothing/combustible materials.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H272-H315-H319-H335
May intensify fire; oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Quantity 1g
DOT Information Transport Hazard Class: 5.1; Packing Group: III; Proper Shipping Name: OXIDIZING SOLID, N.O.S.
Synonym DMP; 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one
Merck Index 14,2933

Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.

Safety and Handling

Danger

GHS P Statement
P221-P210-P220-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep/Store away from clothing/combustible materials.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H272-H315-H319-H335
May intensify fire; oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

−30° to −10°C