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Alfa Aesar™ Dess-Martin periodinane

Manufacturer:  Alfa Aesar™ L1577903

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Catalog No. AAL1577903



Description

Description

Applications
Dess Martin periodinane is used to oxidize primary alcohols to aldehydes and secondary alcohols to ketones. It is also used as an oxidant for complexes with multifunctional alcohols. It is actively involved in the oxidation of N-protected-amino alcohols without epimerization and allylic alcohols.

Solubility
Soluble in chloroform, acetone, acetonitrile and methylene chloride. Slightly soluble in ether and hexane.

Notes
Store in cool place. Air and moisture sensitive. Incompatible with strong reducing agents, combustible material and water.
Specifications

Specifications

Dess-Martin periodinane
87413-09-0
C13H13IO8
UN1479
14,2933
NKLCNNUWBJBICK-UHFFFAOYSA-N
(1,1-diacetyloxy-3-oxo-1$l^{5},2-benziodoxol-1-yl) acetate
159087
≥95%
130°C to 132°C
1g
MFCD00130127
4548207
1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3 1h-one
CC(=O)OI1(C2=CC=CC=C2C(=O)O1)(OC(=O)C)OC(=O)C
424.143
424.15

Chemical Identifiers

87413-09-0
424.143
NKLCNNUWBJBICK-UHFFFAOYSA-N
159087
CC(=O)OI1(C2=CC=CC=C2C(=O)O1)(OC(=O)C)OC(=O)C
C13H13IO8
MFCD00130127
1,1,1-triacetoxy-1,1-dihydro-1,2-benziodoxol-3 1h-one
(1,1-diacetyloxy-3-oxo-1$l^{5},2-benziodoxol-1-yl) acetate
Safety and Handling

Safety and Handling

GHS H Statement
H272-H315-H319-H335
May intensify fire; oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P221-P210-P220-P305+P351+P338-P405-P501a
Take any precaution to avoid mixing with combustibles.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep/Store away from clothing/combustible materials.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 5.1; Packing Group: III; Proper Shipping Name: OXIDIZING SOLID, N.O.S.

Recommended Storage : −30° to −10°C

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