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Alfa Aesar™ Chloromethyl methyl sulfide, 95%

Manufacturer:  Alfa Aesar™ L1085809

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Catalog No. AAL1085809



Description

Description

Applications
Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

Solubility
Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature: 2 - 8°C. Incompatible with strong oxidizing agents.
Specifications

Specifications

Chloromethyl methyl sulfide
Stench
10g
C2H5ClS
UN1993
chloromethyl methyl sulfide, chlorodimethyl sulfide, methylthiomethyl chloride, chloro methylthio methane, methane, chloro methylthio, chlorodimethyl thioether, chloromethyl methyl thioether, monochlorodimethyl sulfide, chloro methylsulfanyl methane, clorodimetilsolfuro
CSCCl
96.572
96.58
17°C (62°F)
104°C to 105°C
2373-51-5
MFCD00000923
1730851
JWMLCCRPDOIBAV-UHFFFAOYSA-N
chloro(methylsulfanyl)methane
16916
95%

Chemical Identifiers

2373-51-5
96.572
JWMLCCRPDOIBAV-UHFFFAOYSA-N
16916
CSCCl
C2H5ClS
MFCD00000923
chloromethyl methyl sulfide, chlorodimethyl sulfide, methylthiomethyl chloride, chloro methylthio methane, methane, chloro methylthio, chlorodimethyl thioether, chloromethyl methyl thioether, monochlorodimethyl sulfide, chloro methylsulfanyl methane, clorodimetilsolfuro
chloro(methylsulfanyl)methane
Safety and Handling

Safety and Handling

GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapor.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Avoid breathing dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.

RTECSNumber : WQ3700000

Recommended Storage : 2° to 8°C

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