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Alfa Aesar™ Chlorodi(p-tolyl)phosphine, 95%

Chemical Identifiers

Chemical Name or Material Chlorodi(p-tolyl)phosphine
CAS 1019-71-2
Molecular Formula C14H14ClP
Formula Weight 248.69g/mol
MDL Number MFCD01630844
UN Number UN1760
Synonym Di(p-tolyl)chlorophosphine; Chlorobis(4-methylphenyl)phosphine
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAH2588903

 
alfa aesar™
H25889-03
1g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAH2588906

 
alfa aesar™
H25889-06
5g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Boiling Point 180° to 184°C (10mmHg)
Quantity 1g
Chemical Name or Material Chlorodi(p-tolyl)phosphine
CAS 1019-71-2
Assay 95%
Molecular Formula C14H14ClP
Formula Weight 248.69g/mol
MDL Number MFCD01630844
UN Number UN1760
Synonym Di(p-tolyl)chlorophosphine; Chlorobis(4-methylphenyl)phosphine
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3 GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUIDS, N.O.S.

Applications
Chlorodi(p-tolyl)phosphine is used as a reactant for synthesis of palladium catalysts for C-C bond forming cross-coupling reactions, ligands for nickel(0)-catalyzed isomerization reactions, phosphinosulfonamide nickel complexes for oligomerization reactions. It is a reactant for phosphinylation reactions.

Solubility
Reacts with water.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents, water/ moisture.

Safety and Handling

Danger

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.