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Alfa Aesar™ Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 98+%, may contain suspended dimethylamine hydrochloride crystals

$123.81 - $368.91

Chemical Identifiers

Chemical Name or Material Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine
CAS 142421-57-6
Molecular Formula C16H6ClF12P
Formula Weight 492.63g/mol
MDL Number MFCD01630852
UN Number UN3265
Synonym Bis[3,5-bis(trifluoromethyl)phenyl]chlorophosphine
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAH2588303

 
alfa aesar™
H25883-03
1g Each for $123.81

AAH2588306

 
alfa aesar™
H25883-06
5g Each for $368.91
Description & Specifications

Specifications

Quantity 1g
Chemical Name or Material Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine
CAS 142421-57-6
Assay ≥98%
Assay Percent Notes may contain suspended dimethylamine hydrochloride crystals
Molecular Formula C16H6ClF12P
Formula Weight 492.63g/mol
MDL Number MFCD01630852
UN Number UN3265
Synonym Bis[3,5-bis(trifluoromethyl)phenyl]chlorophosphine
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3 GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

Applications
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

Solubility
Reacts with water.

Notes
Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.

Safety and Handling

Danger

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.