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Alfa Aesar™ Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4

$82.35 - $320.18

Chemical Identifiers

CAS 14044-65-6
Molecular Formula C4H11BO
Linear Formula BH3/(CH2)4O
Formula Weight 85.94
MDL Number MFCD00012429
UN Number UN3148
Beilstein 3668402
Synonym BTHF
Chemical Name or Material Borane-tetrahydrofuran Complex, stabilized with 5mmol NaBH4
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Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL13961AE SDS Alfa Aesar™
L13961AE
100mL Each for $82.35
AAL13961AP SDS Alfa Aesar™
L13961AP
500mL Each for $320.18
AAL13961AC SDS Alfa Aesar™
L13961AC
25mL N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Specifications

Description

Applications
Borane-tetrahydrofuran complex is an important reagent used in the reduction of certain functional groups viz. aldehyde, ketone, carboxylic acid, amide, oxime, imine and nitrile. It is also used as hydro borating agent. It acts as a borane source for oxazaborolidine catalyzed asymmetric reductions. It is utilized to reduce nylon surface amide groups to secondary amines.

Solubility
Miscible and reacts violently with water.

Notes
Air and moisture sensitive. Forms explosive peroxides in contact with air. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents and alcohols. On hydrolysis, it forms hydrogen and boric acid.
Description & Specifications

Chemical Identifiers

14044-65-6
BH3/(CH2)4O
MFCD00012429
3668402
Borane-tetrahydrofuran Complex, stabilized with 5mmol NaBH4
C4H11BO
85.94
UN3148
BTHF

Specifications

14044-65-6
BH3/(CH2)4O
MFCD00012429
3668402
BTHF
−21°C (−8°F)
C4H11BO
85.94
UN3148
1M soln. in THF
100mL
Borane-tetrahydrofuran Complex, stabilized with 5mmol NaBH4

Safety and Handling

GHS H Statement
H225-H260-H318-H351-H302-H335-H315
Highly flammable liquid and vapor.
In contact with water releases flammable gases which may ignite spontaneously.
Causes serious eye damage.
Suspected of causing cancer.
Harmful if swallowed.
May cause respiratory irritation.
Causes skin irritation.

GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: WATER-REACTIVE LIQUID, N.O.S.

TSCA : TSCA

Recommended Storage : 2° to 8°C