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Alfa Aesar™ Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4

Manufacturer:  Alfa Aesar™ L13961AE

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Catalog No. AAL13961AE



Description

Description

Applications
Borane-tetrahydrofuran complex is an important reagent used in the reduction of certain functional groups viz. aldehyde, ketone, carboxylic acid, amide, oxime, imine and nitrile. It is also used as hydro borating agent. It acts as a borane source for oxazaborolidine catalyzed asymmetric reductions. It is utilized to reduce nylon surface amide groups to secondary amines.

Solubility
Miscible and reacts violently with water.

Notes
Air and moisture sensitive. Forms explosive peroxides in contact with air. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents and alcohols. On hydrolysis, it forms hydrogen and boric acid.
Specifications

Specifications

Borane-tetrahydrofuran Complex
100mL
14044-65-6
BH3/(CH2)4O
UN3148
borane-tetrahydrofuran complex, tetrahydrofuran borane, bh3.thf, borane tetrahydrofuran complex solution, borane-d3-thf complex solution, borane-tetrahydrofuran, unii-5ear4err1l, oxolane borane, boron; oxolane, borane thf
UWTDFICHZKXYAC-UHFFFAOYSA-N
boron;oxolane
11062302
−21°C (−8°F)
stabilized with 5mmol NaBH4
C4H8BO
MFCD00012429
3668402
1M soln. in THF
[B].C1CCOC1
82.917
85.94

Chemical Identifiers

14044-65-6
82.917
UWTDFICHZKXYAC-UHFFFAOYSA-N
11062302
[B].C1CCOC1
C4H8BO
MFCD00012429
borane-tetrahydrofuran complex, tetrahydrofuran borane, bh3.thf, borane tetrahydrofuran complex solution, borane-d3-thf complex solution, borane-tetrahydrofuran, unii-5ear4err1l, oxolane borane, boron; oxolane, borane thf
boron;oxolane
Safety and Handling

Safety and Handling

GHS H Statement
H225-H260-H318-H351-H302-H335-H315
Highly flammable liquid and vapor.
In contact with water releases flammable gases which may ignite spontaneously.
Causes serious eye damage.
Suspected of causing cancer.
Harmful if swallowed.
May cause respiratory irritation.
Causes skin irritation.

GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Danger

DOTInformation : Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: WATER-REACTIVE LIQUID, N.O.S.

TSCA : TSCA

Recommended Storage : 2° to 8°C

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