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Alfa Aesar™ Bismuth(III) trifluoromethanesulfonate, 99%

Chemical Identifiers

Chemical Name or Material Bismuth(III) trifluoromethanesulfonate
CAS 88189-03-1
Molecular Formula C3BiF9O9S3
Linear Formula (CF3SO3)3Bi
Formula Weight 656.19g/mol
MDL Number MFCD02093669
UN Number UN3261
Synonym Bismuth triflate; Trifluoromethanesulfonic acid bismuth salt
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1968706

 
alfa aesar™
L19687-06
5g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAL1968714

 
alfa aesar™
L19687-14
25g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Quantity 5g
Melting Point >300°C
Quantity 5g
Chemical Name or Material Bismuth(III) trifluoromethanesulfonate
CAS 88189-03-1
Assay 99%
Molecular Formula C3BiF9O9S3
Linear Formula (CF3SO3)3Bi
Formula Weight 656.19g/mol
MDL Number MFCD02093669
UN Number UN3261
Synonym Bismuth triflate; Trifluoromethanesulfonic acid bismuth salt
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
Health Hazard 3 GHS P Statement
P280-P303+P361+P353-P305+P351+P338-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
DOT Information Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.

Applications
Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.

Solubility
Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.

Notes
Hygroscopic. Incompatible with strong oxidizing agents.

Safety and Handling

Danger

GHS P Statement
P280-P303+P361+P353-P305+P351+P338-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.