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Alfa Aesar™ Bismuth(III) trifluoromethanesulfonate, 99%

Chemical Identifiers

CAS 88189-03-1
Molecular Formula C3BiF9O9S3
Linear Formula (CF3SO3)3Bi
Formula Weight 656.19
MDL Number MFCD02093669
UN Number UN3261
Synonym Bismuth triflate; Trifluoromethanesulfonic acid bismuth salt
Chemical Name or Material Bismuth(III) trifluoromethanesulfonate
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL1968706 SDS Alfa Aesar™
L1968706
5g N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
AAL1968714 SDS Alfa Aesar™
L1968714
25g N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Specifications

Description

Applications
Bismuth(III) trifluoromethanesulfonate acts as a catalyst in Friedel-Crafts acylation and cycloisomerization of allene-enol ethers. It behaves as a direct substitution catalyst and involved in the substitution of allylic, propargylic, and benzylic alcohols with sulfonamides, carboxamides and carbamates. Further, it is also used in Mukaiyama aldol reactions.

Solubility
Soluble in organics acetonitrile, dioxane, dimethyl formamide and dimethyl sulfoxide.

Notes
Hygroscopic. Incompatible with strong oxidizing agents.
Description & Specifications

Chemical Identifiers

88189-03-1
(CF3SO3)3Bi
MFCD02093669
Bismuth triflate; Trifluoromethanesulfonic acid bismuth salt
C3BiF9O9S3
656.19
UN3261
Bismuth(III) trifluoromethanesulfonate

Specifications

88189-03-1
>300°C
656.19
5g
Bismuth triflate; Trifluoromethanesulfonic acid bismuth salt
99%
C3BiF9O9S3
(CF3SO3)3Bi
MFCD02093669
UN3261
Bismuth(III) trifluoromethanesulfonate

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

GHS P Statement
P280-P303+P361+P353-P305+P351+P338-P310
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Danger

DOTInformation : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.