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Bismuth(III) chloride, 97+% (dry wt.), may cont. up to 3% water, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A1051022

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Catalog No. AAA1051022



Description

Description

Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Bismuth(III) chloride is used as a catalyst in organic synthesis and to prepare other bismuth salts. It is used as a starting material for the preparation of bismuthoxychloride upon hydrolysis. It is an oxidizing agent to prepare metallic bismuth by reducing agent. Further, it catalyzes the Michael reaction and the Mukaiyama-aldol reaction. In addition to this, it is a Lewis acid.

Solubility
Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.

Notes
Hygroscopic. Incompatible with strong oxidizing agents.
Specifications

Specifications

∼430°C (sublimation)
230°C to 232°C
100 g
BiCl3
UN3260
bismuth trichloride, bismuth chloride, trichlorobismuthine, trichlorobismuth, bismuth iii chloride, bismuthine, trichloro, trichlorobismute, bismuth lll chloride
JHXKRIRFYBPWGE-UHFFFAOYSA-K
trichlorobismuthane
24591
98%
Irritating
4.75
Bismuth (III) chloride
7787-60-2
(dry wt.)
MFCD00003461
14,1262
Soluble in hydrochloric acid,nitric acid,diethyl ether,ethyl acetate and acetone. Insoluble in alcohol.
Cl[Bi](Cl)Cl
315.33
315.34
May contain up to 3% water
Moisture sensitive

Chemical Identifiers

7787-60-2
315.33
JHXKRIRFYBPWGE-UHFFFAOYSA-K
24591
Cl[Bi](Cl)Cl
BiCl3
MFCD00003461
bismuth trichloride, bismuth chloride, trichlorobismuthine, trichlorobismuth, bismuth iii chloride, bismuthine, trichloro, trichlorobismute, bismuth lll chloride
trichlorobismuthane
Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

DOTInformation : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE SOLID, ACIDIC, INORGANIC, N.O.S.

EINECSNumber : 232-123-2

RTECSNumber : EB2690000

TSCA : Yes

Recommended Storage : Ambient temperatures

SDS
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