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Alfa Aesar™ [Bis(trifluoroacetoxy)iodo]benzene, 97%

$52.05 - $140.35

Chemical Identifiers

Chemical Name or Material [Bis(trifluoroacetoxy)iodo]benzene
CAS 2712-78-9
Molecular Formula C10H5F6IO4
Formula Weight 430.04g/mol
MDL Number MFCD00009672
Beilstein 764767
Synonym BTI; Iodosobenzene bis(trifluoroacetate)
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1514114

 
alfa aesar™
L15141-14
25g Each for $140.35

AAL1514106

 
alfa aesar™
L15141-06
5g Each for $52.05
Description & Specifications

Specifications

Melting Point 122° to 125°C
Quantity 25g
Chemical Name or Material [Bis(trifluoroacetoxy)iodo]benzene
CAS 2712-78-9
Assay 97%
Molecular Formula C10H5F6IO4
Formula Weight 430.04g/mol
MDL Number MFCD00009672
Beilstein 764767
Synonym BTI; Iodosobenzene bis(trifluoroacetate)
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Recommended Storage 2° to 8°C

Applications
[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

Solubility
Insoluble in water.

Notes
Light and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

2° to 8°C