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Alfa Aesar™ [Bis(trifluoroacetoxy)iodo]benzene, 97%

$52.34 - $140.99

Chemical Identifiers

CAS 2712-78-9
Molecular Formula C10H5F6IO4
Formula Weight 430.04
MDL Number MFCD00009672
Beilstein 764767
Synonym BTI; Iodosobenzene bis(trifluoroacetate)
Chemical Name or Material [Bis(trifluoroacetoxy)iodo]benzene
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL1514114 SDS Alfa Aesar™
L1514114
25g Each for $140.99
AAL1514106 SDS Alfa Aesar™
L1514106
5g Each for $52.34
Specifications

Description

Applications
[Bis(trifluoroacetoxy)iodo]benzene acts as a reagent in Pummerer-like reactions. It plays an important role in the direct alfa-hydroxylation of ketones under acidic conditions. It is involved in the cyclization of styryl amines to N-alkyl or N-aryl indoles. It serves as a reagent for the chemoselective deprotection of dimethoxybenzyl ethers and tosyloxylation of anilides. Further, it is used in the synthesis of 1,3,4-oxadiazoles by the oxidation of N-acylhydrazones. In addition to this, it is employed in the Hofmann rearrangement for the conversion of cyclobutanecarboxamide to cyclobutylamine hydrochloride.

Solubility
Insoluble in water.

Notes
Light and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases.
Description & Specifications

Chemical Identifiers

2712-78-9
430.04
764767
[Bis(trifluoroacetoxy)iodo]benzene
C10H5F6IO4
MFCD00009672
BTI; Iodosobenzene bis(trifluoroacetate)

Specifications

2712-78-9
430.04
764767
122° to 125°C
[Bis(trifluoroacetoxy)iodo]benzene
C10H5F6IO4
MFCD00009672
BTI; Iodosobenzene bis(trifluoroacetate)
25g
97%

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Warning

Recommended Storage : 2° to 8°C