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Alfa Aesar™ Allyltri-n-butyltin, 97%

Chemical Identifiers

Chemical Name or Material Allyltri-n-butyltin
CAS 24850-33-7
Molecular Formula C15H32Sn
Formula Weight 331.12g/mol
MDL Number MFCD00010346
UN Number UN2788
Beilstein 3588340
Synonym Allyltri-n-butylstannane; Tri-n-butyl-2-propenylstannane
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1408706

 
alfa aesar™
L14087-06
5g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAL1408714

 
alfa aesar™
L14087-14
25g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Boiling Point 100° to 102°C (0.5mmHg)
Quantity 5g
Flash Point 103°C (217°F)
Quantity 5g
Chemical Name or Material Allyltri-n-butyltin
CAS 24850-33-7
Assay 97%
Molecular Formula C15H32Sn
Formula Weight 331.12g/mol
MDL Number MFCD00010346
UN Number UN2788
Beilstein 3588340
Synonym Allyltri-n-butylstannane; Tri-n-butyl-2-propenylstannane
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H301-H372-H312-H315-H319
Toxic if swallowed.
Causes damage to organs through prolonged or repeated exposure.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
Health Hazard 3 GHS P Statement
P260-P280-P301+P310-P305+P351+P338-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Recommended Storage 2° to 8°C
DOT Information Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: ORGANOTIN COMPOUNDS, LIQUID, N.O.S.

Applications
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

Solubility
Immiscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.

Safety and Handling

Danger

GHS P Statement
P260-P280-P301+P310-P305+P351+P338-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H301-H372-H312-H315-H319
Toxic if swallowed.
Causes damage to organs through prolonged or repeated exposure.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.

2° to 8°C