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Alfa Aesar™ Allylboronic acid pinacol ester, 98+%

Chemical Identifiers

CAS 72824-04-5
Molecular Formula C9H17BO2
Formula Weight 168.05
MDL Number MFCD00013347
UN Number UN3272
Beilstein 4244068
Synonym 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
Chemical Name or Material Allylboronic acid pinacol ester
View More Specs


Products ${productFamilyLength}
Catalog Number Mfr. No. Quantity Price Quantity  
Catalog Number Mfr. No. Quantity Price Quantity  
AAL1623203 SDS Alfa Aesar™
L1623203
1g N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
AAL1623206 SDS Alfa Aesar™
L1623206
5g N/A N/A  
Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Specifications

Description

Applications
Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.

Solubility
Not miscible or difficult to mix in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature is 2 - 8°C. Store under inert gas. It is sensitive to moisture. Incompatible with oxidizing agents.
Description & Specifications

Chemical Identifiers

72824-04-5
168.05
UN3272
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
C9H17BO2
MFCD00013347
4244068
Allylboronic acid pinacol ester

Specifications

72824-04-5
168.05
UN3272
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1g
Allylboronic acid pinacol ester
C9H17BO2
MFCD00013347
4244068
50° to 53°C (5mmHg)
46°C (140°F)
≥98%

Safety and Handling

GHS H Statement
H226
Flammable liquid and vapor.

GHS P Statement
P210-P280-P240-P303+P361+P353-P403+P235-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Wear protective gloves/protective clothing/eye protection/face protection.
Ground/bond container and receiving equipment.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Warning

DOTInformation : Transport Hazard Class: 3; Packing Group: III; Proper Shipping Name: ESTERS, N.O.S.