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4-Chlorobenzeneboronic acid, 98+%, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals A1565714

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Catalog No. AAA1565714



Description

Description

Used as a GC reagent for diols. It is a reagent used for palladium-catalyzed direct arylation, cyclopalladation, tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation, copper-mediated ligandless aerobic fluoroalkylation, Pd-catalyzed arylative cyclization, ruthenium catalyzed direct arylation, ligand-free copper-catalyzed coupling reactions and regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions. Also in as a reagent in the preparation of catalysts for Suzuki-Miyaura cross-coupling, palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts, Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Used as a GC reagent for diols. It is a reagent used for palladium-catalyzed direct arylation, cyclopalladation, tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation, copper-mediated ligandless aerobic fluoroalkylation, Pd-catalyzed arylative cyclization, ruthenium catalyzed direct arylation, ligand-free copper-catalyzed coupling reactions and regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions. Also in as a reagent in the preparation of catalysts for Suzuki-Miyaura cross-coupling, palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts, Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.

Solubility
Slightly soluble in water. Soluble in DMSO.

Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications

Specifications

4-Chlorobenzeneboronic acid
1679-18-1
C6H6BClO2
2936346
Slightly soluble in water. Soluble in DMSO.
OB(O)C1=CC=C(Cl)C=C1
156.37
156.38
268°C to 277°C
25 g
MFCD00039137
4-chlorophenyl boronic acid, 4-chlorobenzeneboronic acid, p-chlorophenylboronic acid, benzeneboronic acid, p-chloro, p-chlorobenzeneboronic acid, boronic acid, 4-chlorophenyl, boronic acid, p-chlorophenyl, 4-chlorophenyl boranediol, 4-chlorophenylbornic acid
CAYQIZIAYYNFCS-UHFFFAOYSA-N
(4-chlorophenyl)boronic acid
74299
≥98%

Chemical Identifiers

1679-18-1
156.37
CAYQIZIAYYNFCS-UHFFFAOYSA-N
74299
OB(O)C1=CC=C(Cl)C=C1
C6H6BClO2
MFCD00039137
4-chlorophenyl boronic acid, 4-chlorobenzeneboronic acid, p-chlorophenylboronic acid, benzeneboronic acid, p-chloro, p-chlorobenzeneboronic acid, boronic acid, 4-chlorophenyl, boronic acid, p-chlorophenyl, 4-chlorophenyl boranediol, 4-chlorophenylbornic acid
(4-chlorophenyl)boronic acid
Safety and Handling

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c

H302-H315-H319-H335

EINECSNumber : 216-845-5

RTECSNumber : CY8950000

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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