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4-Chlorobenzeneboronic acid, 98+%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals A1565714
Description
Used as a GC reagent for diols. It is a reagent used for palladium-catalyzed direct arylation, cyclopalladation, tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation, copper-mediated ligandless aerobic fluoroalkylation, Pd-catalyzed arylative cyclization, ruthenium catalyzed direct arylation, ligand-free copper-catalyzed coupling reactions and regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions. Also in as a reagent in the preparation of catalysts for Suzuki-Miyaura cross-coupling, palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts, Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsUsed as a GC reagent for diols. It is a reagent used for palladium-catalyzed direct arylation, cyclopalladation, tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation, copper-mediated ligandless aerobic fluoroalkylation, Pd-catalyzed arylative cyclization, ruthenium catalyzed direct arylation, ligand-free copper-catalyzed coupling reactions and regioselective arylation and alkynylation by Suzuki-Miyaura and Sonogashira cross-coupling reactions. Also in as a reagent in the preparation of catalysts for Suzuki-Miyaura cross-coupling, palladium(II) thiocarboxamide complexes as Suzuki coupling catalysts, Biaryls by Suzuki reactions of aryl chlorides, bromides, and iodides with arylboronic acids.
Solubility
Slightly soluble in water. Soluble in DMSO.
Notes
Store away from oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
Specifications
4-Chlorobenzeneboronic acid | |
1679-18-1 | |
C6H6BClO2 | |
2936346 | |
Slightly soluble in water. Soluble in DMSO. | |
OB(O)C1=CC=C(Cl)C=C1 | |
156.37 | |
156.38 |
268°C to 277°C | |
25 g | |
MFCD00039137 | |
4-chlorophenyl boronic acid, 4-chlorobenzeneboronic acid, p-chlorophenylboronic acid, benzeneboronic acid, p-chloro, p-chlorobenzeneboronic acid, boronic acid, 4-chlorophenyl, boronic acid, p-chlorophenyl, 4-chlorophenyl boranediol, 4-chlorophenylbornic acid | |
CAYQIZIAYYNFCS-UHFFFAOYSA-N | |
(4-chlorophenyl)boronic acid | |
74299 | |
≥98% |
Chemical Identifiers
1679-18-1 | |
156.37 | |
CAYQIZIAYYNFCS-UHFFFAOYSA-N | |
74299 | |
OB(O)C1=CC=C(Cl)C=C1 |
C6H6BClO2 | |
MFCD00039137 | |
4-chlorophenyl boronic acid, 4-chlorobenzeneboronic acid, p-chlorophenylboronic acid, benzeneboronic acid, p-chloro, p-chlorobenzeneboronic acid, boronic acid, 4-chlorophenyl, boronic acid, p-chlorophenyl, 4-chlorophenyl boranediol, 4-chlorophenylbornic acid | |
(4-chlorophenyl)boronic acid |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P305+P351+P338-P312-P330-P332+P313-P362-P501c
H302-H315-H319-H335
EINECSNumber : 216-845-5
RTECSNumber : CY8950000
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only