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Alfa Aesar™ 4-Bromotoluene, 98%

$31.34 - $173.28

Chemical Identifiers

Chemical Name or Material 4-Bromotoluene
CAS 106-38-7
Molecular Formula C7H7Br
Formula Weight 171.04
MDL Number MFCD00000109
Beilstein 1903636
Merck Index 14,1439
Synonym 4-Methylbromobenzene
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1584314

  SDS
alfa aesar™
A1584314
25g Each for $31.34

AAA1584322

  SDS
alfa aesar™
A1584322
100g Each for $62.53

AAA1584336

  SDS
alfa aesar™
A1584336
500g Each for $173.28
Description & Specifications

Specifications

Formula Weight 171.04
Melting Point 26° to 29°C
Assay 98%
Flash Point 85°C (185°F)
CAS 106-38-7
Chemical Name or Material 4-Bromotoluene
Beilstein 1903636
Boiling Point 183° to 184°C
Synonym 4-Methylbromobenzene
Quantity 25g
RTECS Number XS7965600
Molecular Formula C7H7Br
Health Hazard 1 Danger
Merck Index 14,1439
Health Hazard 2 GHS H Statement
H301-H315-H319-H335
Toxic if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
TSCA TSCA
MDL Number MFCD00000109
Health Hazard 3 GHS P Statement
P261-P280-P301+P310-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Applications
4-Bromotoluene was used in the synthesis of ketones by Cu/Pd-catalyzed decarboxylative cross-coupling reaction. 4-Bromotoluene undergoes Heck reaction with styrene in the presence of in situ generated palladium complexes of phosphine-functionalized N-heterocyclic carbene ligands.

Solubility
Insoluble in water. Soluble in methanol.

Notes
Store at room temperature. Keep away from oxidizing agents.

Safety and Handling

Danger

GHS P Statement
P261-P280-P301+P310-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H301-H315-H319-H335
Toxic if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.