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Alfa Aesar™ 3-(Methoxycarbonyl)benzeneboronic acid, 97%

$257.46 - $257.46

Chemical Identifiers

Chemical Name or Material 3-(Methoxycarbonyl)benzeneboronic acid
CAS 99769-19-4
Molecular Formula C8H9BO4
Formula Weight 179.97g/mol
MDL Number MFCD02093046
Synonym 3-(Methoxycarbonyl)phenylboronic acid; Methyl 3-boronobenzoate
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAH2744406

 
alfa aesar™
H27444-06
5g Each for $257.46
Description & Specifications

Specifications

Melting Point 136°C
Quantity 5g
Chemical Name or Material 3-(Methoxycarbonyl)benzeneboronic acid
CAS 99769-19-4
Assay 97%
Molecular Formula C8H9BO4
Formula Weight 179.97g/mol
MDL Number MFCD02093046
Synonym 3-(Methoxycarbonyl)phenylboronic acid; Methyl 3-boronobenzoate
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Applications
Reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration, cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. Reagent used in Preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6, chromenones and their bradykinin B1 antagonistic active, Pt nanoparticles at Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injecti, salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.