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Alfa Aesar™ 3,4-(Methylenedioxy)aniline, 98+%

Chemical Identifiers

Chemical Name or Material 3,4-(Methylenedioxy)aniline
CAS 14268-66-7
Molecular Formula C7H7NO2
Formula Weight 137.14g/mol
MDL Number MFCD00005832
UN Number UN2811
Beilstein 4919
Synonym 5-Amino-1,3-benzodioxole; 1,3-Benzodioxol-5-amine
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1297518

 
alfa aesar™
A12975-18
50g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAA1297530

 
alfa aesar™
A12975-30
250g CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Melting Point 40° to 45°C
Boiling Point 144°C (16mmHg)
Quantity 50g
Flash Point 142°C (287°F)
Chemical Name or Material 3,4-(Methylenedioxy)aniline
CAS 14268-66-7
Assay ≥98%
Molecular Formula C7H7NO2
Formula Weight 137.14g/mol
MDL Number MFCD00005832
UN Number UN2811
Beilstein 4919
Synonym 5-Amino-1,3-benzodioxole; 1,3-Benzodioxol-5-amine
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H331-H302-H312-H315-H319
Toxic if inhaled.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 6.1; Packing Group: III; Proper Shipping Name: TOXIC SOLIDS, ORGANIC, N.O.S.
TSCA TSCA

Applications
3,4-(Methylenedioxy)aniline is an pharmaceutically important aniline derivative. It undergoes N-alkylation with cyclic secondary alkylamines in the presence of Shvo catalyst to yield N-arylpyrrolidines. 3,4-(Methylenedioxy)aniline was used in the synthesis of γ-glutamylanilides.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible to strong acids, acid chlorides, acid anhydrides. Air & Light Sensitive. Stable under recommended storage conditions.

Safety and Handling

Danger

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H331-H302-H312-H315-H319
Toxic if inhaled.
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.