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Alfa Aesar™ 2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine, 99%

$52.35 - $186.01

Chemical Identifiers

Chemical Name or Material 2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine
CAS 145100-51-2
Molecular Formula C7H3ClF6N2O4S2
Formula Weight 392.68g/mol
MDL Number MFCD00191833
Beilstein 5833971
Synonym 2-[N,N-Bis(trifluoromethanesulfonyl)amino]-5-chloropyridine; N-(5-Chloro-2-pyridyl)triflimide
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAL1692903

 
alfa aesar™
L16929-03
1g Each for $52.35

AAL1692906

 
alfa aesar™
L16929-06
5g Each for $186.01
Description & Specifications

Specifications

Melting Point 44° to 47°C
Quantity 1g
Chemical Name or Material 2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine
CAS 145100-51-2
Assay 99%
Molecular Formula C7H3ClF6N2O4S2
Formula Weight 392.68g/mol
MDL Number MFCD00191833
Beilstein 5833971
Synonym 2-[N,N-Bis(trifluoromethanesulfonyl)amino]-5-chloropyridine; N-(5-Chloro-2-pyridyl)triflimide
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Recommended Storage 2° to 8°C

Applications
2-[N,N-Bis(trifluoromethylsulfonyl)amino]-5-chloropyridine provides good yields of vinyl triflates from the corresponding ketone enolates or dienolates. It is used in the total synthesis of (-)-porantheridine and the trans decahydroquinoline alkaloid (+)-219A. It is also used as a reactant for Suzuki-Miyaura cross coupling, synthesis of nicotinic acetylcholine receptor-selective ligands, enantioselective desymmetrizing palladium catalyzed carbonylation reactions, synthesis of high affinity niacin receptor GPR109A agonists and in preparation of heteroaromatics.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store under dry inert gas. It is sensitive to moisture.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

2° to 8°C