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Alfa Aesar™ 2-Butenylmagnesium chloride, 0.5M in MeTHF

Chemical Identifiers

Chemical Name or Material 2-Butenylmagnesium chloride
CAS 22649-70-3
Molecular Formula C4H7ClMg
Linear Formula CH3CH=CHCH2MgCl
Formula Weight 114.86
MDL Number MFCD01321226
UN Number UN3399
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAH51171AE

  SDS
alfa aesar™
H51171AE
100mL CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.

AAH51171AP

  SDS
alfa aesar™
H51171AP
500mL CALL N/A N/A
 Please call Customer Service at 1-800-234-7437 or send an email to help@thermofisher.com for assistance.
Description & Specifications

Specifications

Formula Weight 114.86
Chemical Name or Material 2-Butenylmagnesium chloride
Molecular Formula C4H7ClMg
Linear Formula CH3CH=CHCH2MgCl
MDL Number MFCD01321226
CAS 22649-70-3
UN Number UN3399
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Concentration 0.5M in MeTHF
Quantity 100mL
Health Hazard 3 GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE

Applications
2-Butenylmagnesium chloride is used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

Solubility
It reacts violently with water.

Notes
Air & moisture sensitive. Incompatible with oxidizing agents and bases.

Safety and Handling

Danger

GHS P Statement
P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Handle under inert gas.
Protect from moisture.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.