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Alfa Aesar™ (1S,2R)-(-)-10,2-Camphorsultam, 99%

$87.88 - $328.26

Chemical Identifiers

Chemical Name or Material (1S,2R)-(-)-10,2-Camphorsultam
CAS 94594-90-8
Molecular Formula C10H17NO2S
Formula Weight 215.32g/mol
MDL Number MFCD00066271
Beilstein 83811
Synonym (2R)-(-)-Bornane-10,2-sultam
View More Specs
Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAA1589706

 
alfa aesar™
A15897-06
5g Each for $328.26

AAA1589703

 
alfa aesar™
A15897-03
1g Each for $87.88
Description & Specifications

Specifications

Melting Point 181° to 186°C
Quantity 5g
Optical Rotation −33° (c=1 in Ethanol)
Chemical Name or Material (1S,2R)-(-)-10,2-Camphorsultam
CAS 94594-90-8
Assay 99%
Molecular Formula C10H17NO2S
Formula Weight 215.32g/mol
MDL Number MFCD00066271
Beilstein 83811
Synonym (2R)-(-)-Bornane-10,2-sultam
Health Hazard 1 Warning
Health Hazard 2 GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Health Hazard 3 GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Applications
(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.

Solubility
Slightly soluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents.

Safety and Handling

Warning

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.