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(1S,2R)-(-)-10,2-Camphorsultam, 99%, Thermo Scientific Chemicals
Supplier: Thermo Scientific Chemicals A1589714
Description
(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Applications(1S,2R)-(-)-10,2-Camphorsultam is used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It is used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones. It is also employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. Also used to prepare N-acryloyl derivatives which are employed as dienophiles in asymmetric Diels-Alder reactions. and for other asymmetric transformations.
Solubility
Slightly soluble in water.
Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong bases and strong oxidizing agents.
Specifications
(1S,2R)-(-)-10,2-Camphorsultam | |
181°C to 186°C | |
MFCD00066271 | |
83811 | |
Slightly soluble in water. | |
−33° (c=1 in Ethanol) | |
215.311 | |
215.32 |
94594-90-8 | |
C10H17NO2S | |
25 g | |
5r,7r-10,10-dimethyl-3??-thia-4-azatricyclo 5.2.1.0 1 ,? decane-3,3-dione, --10,2-camphorsultam;--exo-10,2-bornanesultam; 3as-3a, a,6, a,7a, a-hexahydro-8,8-dimethyl-3h-3a,6-methano-2,1-benzisothiazole-2,2-dioxide; 1s,5r-10,10-dimethyl-3-thia-4-azatricyclo 5.2.1.01,5 decane 3,3-dioxide | |
DPJYJNYYDJOJNO-SZBHIRRCSA-N | |
CC1(C2CCC13CS(=O)(=O)NC3C2)C | |
54579826 | |
99% |
Chemical Identifiers
94594-90-8 | |
215.311 | |
DPJYJNYYDJOJNO-SZBHIRRCSA-N | |
54579826 |
C10H17NO2S | |
MFCD00066271 | |
5r,7r-10,10-dimethyl-3??-thia-4-azatricyclo 5.2.1.0 1 ,? decane-3,3-dione, --10,2-camphorsultam;--exo-10,2-bornanesultam; 3as-3a, a,6, a,7a, a-hexahydro-8,8-dimethyl-3h-3a,6-methano-2,1-benzisothiazole-2,2-dioxide; 1s,5r-10,10-dimethyl-3-thia-4-azatricyclo 5.2.1.01,5 decane 3,3-dioxide | |
CC1(C2CCC13CS(=O)(=O)NC3C2)C |
Safety and Handling
GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
TSCA : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only