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Alfa Aesar™ 15-Crown-5, 98%

Manufacturer:  Alfa Aesar™ A1226503

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Catalog No. AAA1226503



Description

Description

Applications
15-Crown-5 is used as an efficient phase transfer catalyst and as a complexing agent. It is used to isolate oxonium ion (H7O3)+ salts especially from a solution of tetrchloroauric acid. It catalyzes the O-alkylation of the sodium salts of carboxylic acids in the penicillin and cephalosporin series, thereby facilitating esterification reaction without usage of acid. It is also used to facilitate the Williamson synthesis of ethers with hindered alcohols and sodium hydride. It is used with lithium aluminum hydride, for performing reduction reactions in hydrocarbon solvents. Further, it is involved in the Horner-Wadsworth-Emmons reaction to prepare stilbenes from aldehydes.

Solubility
Miscible with organic solvents.

Notes
Hygroscopic. Moisture sensitive. Incompatible with strong oxidizing agents and strong acids.
Specifications

Specifications

1g
>110°C (230°F)
98%
MFCD00005110
1,4,7,10,13-Pentaoxacyclopentadecane
C1COCCOCCOCCOCCO1
220.265
CHEBI:32401
220.27
15-Crown-5
33100-27-5
C10H20O5
1618144
VFTFKUDGYRBSAL-UHFFFAOYSA-N
1,4,7,10,13-pentaoxacyclopentadecane
36336
150°C to 155°C (0.5mmHg)

Chemical Identifiers

33100-27-5
220.265
VFTFKUDGYRBSAL-UHFFFAOYSA-N
36336
1,4,7,10,13-pentaoxacyclopentadecane
C10H20O5
MFCD00005110
1,4,7,10,13-Pentaoxacyclopentadecane
CHEBI:32401
C1COCCOCCOCCOCCO1
Safety and Handling

Safety and Handling

GHS H Statement
H302-H315-H319-H335
Harmful if swallowed.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

GHS P Statement
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapors/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

Warning

RTECSNumber : SB0200000

TSCA : TSCA

SDS Documents