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Alfa Aesar™ 1-Propylphosphonic acid cyclic anhydride, 50+% w/w soln. in dichloromethane

Chemical Identifiers

Chemical Name or Material 1-Propylphosphonic acid cyclic anhydride
CAS 68957-94-8
Molecular Formula C9H21O6P3
Formula Weight 318.19g/mol
MDL Number MFCD00006583
UN Number UN2922
Beilstein 5079255
Synonym 1-Propanephosphonic acid cyclic anhydride; T3P
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Products
Catalog Number Mfr. No. Quantity Price Quantity    

AAH6358330

 
alfa aesar™
H63583-30
250g CALL N/A N/A
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Description & Specifications

Specifications

Quantity 250g
Concentration ≥50% w/w soln. in dichloromethane
Quantity 250g
Chemical Name or Material 1-Propylphosphonic acid cyclic anhydride
CAS 68957-94-8
Molecular Formula C9H21O6P3
Formula Weight 318.19g/mol
MDL Number MFCD00006583
UN Number UN2922
Beilstein 5079255
Synonym 1-Propanephosphonic acid cyclic anhydride; T3P
Health Hazard 1 Danger
Health Hazard 2 GHS H Statement
H314-H351
Causes severe skin burns and eye damage.
Suspected of causing cancer.
Health Hazard 3 GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.
DOT Information Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: CORROSIVE LIQUIDS, TOXIC, N.O.S.
TSCA TSCA

Applications
1-Propylphosphonic acid cyclic anhydride is used as a reagent for amide/peptide bond formation. It is utilized for condensation reactions and alcohol oxidations. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

Solubility
Miscible with dioxane, terahydrofuran, dimethyl formamide, polar and aprotic organic solvents.

Notes
Moisture sensitive. Incompatible withstrong oxidizing agents.

Safety and Handling

Danger

GHS P Statement
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a
Do not breathe dust/fume/gas/mist/vapors/spray.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
Store locked up.
Dispose of contents/container in accordance with local/regional/national/international regulations.

GHS H Statement
H314-H351
Causes severe skin burns and eye damage.
Suspected of causing cancer.