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1-Propylphosphonic acid cyclic anhydride, 50+% soln. in ethyl acetate, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals L1191109

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Catalog No. AAL1191109



Description

Description

1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

Solubility
Miscible with dichloromethane, dimethyl formamide, dioxane, terahydrofuran, polar and aprotic organic solvents.

Notes
Moisture sensitive. Incompatible withstrong oxidizing agents.
Specifications

Specifications

1-Propylphosphonic acid cyclic anhydride
1.08
−3°C (26°F)
1.419
10 g
5079255
2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, 1,3,5,2,4,6-trioxatriphosphorinane, 2,4,6-tripropyl-, 2,4,6-trioxide, propane phosphonic acid anhydride, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene
PAQZWJGSJMLPMG-UHFFFAOYSA-N
2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide
111923
≥50% soln. in ethyl acetate
68957-94-8
77°C
C9H21O6P3
MFCD00006583
UN2924
Moisture sensitive
Miscible with dichloromethane,dimethyl formamide,dioxane,terahydrofuran,polar and aprotic organic solvents.
CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC
318.182
318.19

Chemical Identifiers

68957-94-8
MFCD00006583
111923
C9H21O6P3
PAQZWJGSJMLPMG-UHFFFAOYSA-N
Safety and Handling

Safety and Handling

GHS H Statement
H225-H314-H336
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.

P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

H225-H314-H335-H336

DOTInformation : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, CORROSIVE, N.O.S.

EINECSNumber : 422-210-5

TSCA : No

Recommended Storage : Ambient temperatures

SDS
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RUO – Research Use Only