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1-Propylphosphonic acid cyclic anhydride, 50+% soln. in DMF, Thermo Scientific Chemicals

Supplier:  Thermo Scientific Chemicals L1927118

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Catalog No. AAL1927118



Description

Description

1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Propylphosphonic acid cyclic anhydride is used in the synthesis of N-acyloxythiazole-2(3H)-thiones. It is also used to promote the synthesis of hydroxamic acids from carboxylic acids. Further, it is employed as an efficient promoter for the Lossen rearrangement to synthesis urea and carbamate derivatives.

Solubility
Miscible with dichloromethane, dioxane, terahydrofuran, polar and aprotic organic solvents.

Notes
Moisture sensitive. Incompatible withstrong oxidizing agents.
Specifications

Specifications

1-Propylphosphonic acid cyclic anhydride
1.09
62°C (143°F)
1.4505
50 g
5079255
2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, unii-i6egd8839n, propane phosphonic acid anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene
PAQZWJGSJMLPMG-UHFFFAOYSA-N
2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide
111923
≥50% soln. in DMF
68957-94-8
153°C
C9H21O6P3
MFCD00006583
UN3265
Moisture sensitive
Miscible with dichloromethane,dioxane,terahydrofuran,polar and aprotic organic solvents.
CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC
318.182
318.19

Chemical Identifiers

68957-94-8
318.182
PAQZWJGSJMLPMG-UHFFFAOYSA-N
111923
CCCP1(=O)OP(=O)(OP(=O)(O1)CCC)CCC
C9H21O6P3
MFCD00006583
2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide, t3p, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane 2,4,6-trioxide, unii-i6egd8839n, propane phosphonic acid anhydride, 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane 2,4,6-trioxide, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in thf, 1-propanephosphonic anhydride in toluene, 1-propanephosphonic anhydride in toluene
2,4,6-tripropyl-1,3,5,2$l^{5},4$l^{5},6$l^{5}-trioxatriphosphinane 2,4,6-trioxide
Safety and Handling

Safety and Handling

GHS H Statement
H360-H314-H332-H227
May damage fertility or the unborn child.
Causes severe skin burns and eye damage.
Harmful if inhaled.
Combustible liquid.

P201-P202-P210-P233-P240-P241-P242-P243-P260-P264b-P271-P281-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

H226-H314-H332-H360D

DOTInformation : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

EINECSNumber : 422-210-5

TSCA : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

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